117367-10-9Relevant academic research and scientific papers
Palladium-Catalyzed Synthesis of Aryl Amides through Silanoate-Mediated Hydrolysis of Nitriles
McPherson, Christopher G.,Livingstone, Keith,Jamieson, Craig,Simpson, Iain
, p. 88 - 92 (2015/12/26)
A procedure for the formation of aryl amides through the palladium-catalyzed coupling of nitriles and aryl bromides, via the formation of intermediary silanoate derived imidate species is reported. Optimization was undertaken and examples of the process are described that furnish the products in up to 86% isolated yield.
A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides
Carbone, Giorgio,Burnley, James,Moses, John E.
supporting information, p. 2759 - 2761 (2013/04/10)
We report here a new catalytic reaction in which, para-nitro azides are acylated by aldehydes to produce amides and molecular nitrogen in a single step. The transformation is believed to proceed via an electron transfer process mediated by the tert-butoxide ion, and catalysed by a thiazolium salt derived species. The Royal Society of Chemistry 2013.
