117661-89-9

Upstream product

• 34370-91-7 3-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 582-52-5 1,2:5,6-diacetone-D-glucose 
• 20031-21-4 1,2-O-isopropylidene-α-D-xylose 
• 42926-89-6 1,2-O-isopropylidene-3-O-benzyl-α-D-glucofuranose 
• 100-39-0 benzyl bromide 
• 101475-83-6 3-O-benzyl-1,2;5,6-di-O-isopropylidene-α-D-glucofuranoside 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 421-83-0 trifluoromethane sulfonyl chloride 

Downstream Products

• 877760-75-3 tetramethyl [3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-xylofuranos-6,6'-diyl]bisphosphonate 
• 148703-38-2 5-(benzylamino)-5-deoxy-1,2-O-isopropylidene-α-D-xylofuranose 
• 1187322-18-4 C₂₉H₃₈N₂O₆ 
• 1187322-19-5 C₂₁H₃₂N₂O₄ 
• 1187322-20-8 C₂₄H₃₃N₃O₈ 
• 1187321-17-0 C₂₈H₄₀N₄O₅ 
• 4613-58-5 5-amino-5-deoxy-1,2-O-isopropylidene-a-D-xylofuranose 
• 131053-22-0 5-deoxy-1,2-O-(1-isopropylidene)-3-O-benzyl-α-D-xylohexofuranonitrile 
• 182552-04-1 2-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-1-trimethylsilanyl-ethanone 
• 877760-80-0 methyl 1,2:3,4-di-O-isopropylidene-α-D-galactopyranos-6-yl [(3S,4S,5R)-4-benzyloxy-3,5-diacetoxy-1-cyclohexenephosphonate] 
• 877760-77-5 dimethyl (3S,4S,5R)-4-benzyloxy-3,5-diacetoxy-1-cyclohexenephosphonate 
• 877760-76-4 dimethyl (3S,4S,5R)-4-benzyloxy-3,5-dihydroxy-1-cyclohexenephosphonate 
• 153237-96-8 (3aR,5R,6S,6aR)-6-Benzyloxy-5-((4R,5R,6R)-4,5-bis-triisopropylsilanyloxy-6-triisopropylsilanyloxymethyl-5,6-dihydro-4H-pyran-2-ylmethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 

Relevant academic research and scientific papers

NOVEL DERIVATIVES OF ACYL CYANOPYRROLIDINES

A compound of formula (I) or a tautomeric form, regioisomer, stereoisomer, solvate, N-oxide or pharmaceutically acceptable salts thereof; wherein 'a' - is selected from the group consisting of substituted or unsubstituted heterocycloalkyl ring and substituted or unsubstituted carbohydrate moiety y is a member selected from -O-, -CO-, -S02-, aminoalkyl or formula (II) wherein, Rw is hydrogen, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl, heteroaryl; x is a member selected from -0-, -S-, -SO-, -S02-, CONR10, NR10CO and -NRd-, or x and y together represent a chemical bond; Z is selected from -CH-, -N-. t is an integer selected from O to 4; with the provisos that when 'a' is substituted or unsubstituted heterocycloalkyl ring then 't' is not O and when y = -CO-, x is not NRd.

Short Synthetic Route to Congeners of the Undecose Antibiotic Herbicidin

The undecose backbone of the herbicidins has been assemled via direct alkylation, hydroxyalkylation, or acylation of the cyclic vinylanion 5 with the xylofuranose triflate 14, aldehyde 6, or acid chloride 10, respectively.

SYNTHESIS OF CHIRAL PYRROLIDINE AND PIPERIDINE GLYCOSIDASE INHIBITORS

There is disclosed a novel method for the syntheses of chiral pyrrolidines and piperidines by the intramolecular ring closure of anomeric mixtures of 4-amino- and 5-amino-2-trifluoromethanesulfonates of methyl furanosides. The novel method preferably prov

Synthesis of homochiral β-hydroxy-α-aminoacids [2S,3R,4R)-3, 4-dihydroxyproline and (2S,3R,4R)-3,4-dihydroxypipecolic acid] and of 1,4-dideoxy-1,4-imino-D-arabinitol [DAB1] and fagomine [1,5-imino-1,2,5-trideoxy-D-arabino-hexitol]

Efficient syntheses from diacetone glucose of 1,4-dideoxy-1, 4-imino-D-arabinitol, (2S,3R,4R)-3,4-dihydroxyproline, fagomine [1,5-imino-1,2,5-trideoxy-D arabino-hexitol], and (2S,3R,4R)-3,4)-3,4-dihydroxpipecolic acid by intramolecular nucleophilic displacement by an amino function of 2-O-trifluoromethanesulphonates of anomeric mixtures of methyl furanosides are reported.