131053-22-0

Upstream product

• 151-50-8 potassium cyanide 
• 117661-89-9 3-O-benzyl-1,2-O-isopropylidene-5-O-trifluoromethanesulphonyl-α-D-xylofuranose 
• 113119-75-8 3-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranuronamide 
• 182298-38-0 3-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranonitrile 
• 42926-89-6 1,2-O-isopropylidene-3-O-benzyl-α-D-glucofuranose 
• 100-39-0 benzyl bromide 
• 101475-83-6 3-O-benzyl-1,2;5,6-di-O-isopropylidene-α-D-glucofuranoside 
• 34370-91-7 3-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose 
• 582-52-5 1,2:5,6-diacetone-D-glucose 

Downstream Products

• 131053-23-1 methyl 3-O-benzyl-5-cyano-5-deoxy-D-xylofuranoside 

Relevant academic research and scientific papers

Metal-Free Iodine-Mediated Deoxygenation of Alcohols in the Position α to Electron-Withdrawing Groups

The use of a substoichiometric amount of molecular iodine in the presence of PPh3 and pyridine effects a direct deoxygenation of primary and secondary alcohols in positions α to a variety of activating electron-withdrawing groups, including ketones, esters, amides, imides and nitrile groups.

A novel deoxygenation of hydroxy groups activated by a vicinal carbonyl group via reaction with Ph3P/I2/imidazole

A new procedure for a direct conversion of an α-hydroxy sugar ester, lactone or amide into the corresponding α-deoxyester, lactone or nitrile using the system Ph3/I2 /imidazole is reported. Its efficiency is illustrated by deoxygenat

SYNTHESIS OF CHIRAL PYRROLIDINE AND PIPERIDINE GLYCOSIDASE INHIBITORS

There is disclosed a novel method for the syntheses of chiral pyrrolidines and piperidines by the intramolecular ring closure of anomeric mixtures of 4-amino- and 5-amino-2-trifluoromethanesulfonates of methyl furanosides. The novel method preferably prov

Synthesis of homochiral β-hydroxy-α-aminoacids [2S,3R,4R)-3, 4-dihydroxyproline and (2S,3R,4R)-3,4-dihydroxypipecolic acid] and of 1,4-dideoxy-1,4-imino-D-arabinitol [DAB1] and fagomine [1,5-imino-1,2,5-trideoxy-D-arabino-hexitol]

Efficient syntheses from diacetone glucose of 1,4-dideoxy-1, 4-imino-D-arabinitol, (2S,3R,4R)-3,4-dihydroxyproline, fagomine [1,5-imino-1,2,5-trideoxy-D arabino-hexitol], and (2S,3R,4R)-3,4)-3,4-dihydroxpipecolic acid by intramolecular nucleophilic displacement by an amino function of 2-O-trifluoromethanesulphonates of anomeric mixtures of methyl furanosides are reported.