117770-09-9

Basic information

• Product Name: N-benzyl-2,3-bis-(O-tert-butyldimethylsilyl)-1,4-dideoxy-5,6-O-isopropylidene-1,4-imino-D-glucitol
• CAS NO: 117770-09-9
• Molecular Weight: 521.888
• Mol File: 117770-09-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzyl-2,3-bis-(O-tert-butyldimethylsilyl)-1,4-dideoxy-5,6-O-isopropylidene-1,4-imino-D-glucitol(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-2,3-bis-(O-tert-butyldimethylsilyl)-1,4-dideoxy-5,6-O-isopropylidene-1,4-imino-D-glucitol(117770-09-9)
• EPA Substance Registry System: N-benzyl-2,3-bis-(O-tert-butyldimethylsilyl)-1,4-dideoxy-5,6-O-isopropylidene-1,4-imino-D-glucitol(117770-09-9)

Safety Data

• Hazardous Substances Data: 117770-09-9(Hazardous Substances Data)

Upstream product

• 2782-07-2 D-galactono-1,4-lactone 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 117770-08-8 2,3-(bis-O-tert-butyldimethylsilyl)-5,6-O-isopropylidene-D-galactono-1,4-lactone 
• 117803-74-4 2,3-bis-(O-tert-butyldimethylsilyl)-1,4-bis-O-(methanesulphonyl)-5,6-O-isopropylidene-D-galactitol 
• 100-46-9 benzylamine 
• 117781-08-5 2,3-bis-(O-tert-butyldimethylsilyl)-5,6-O-isopropylidene-D-galactitol 
• 56710-46-4 5,6-O-isopropylidene-D-galactonic acid γ-lactone 

Downstream Products

• 24578-06-1 1,4-dideoxy-1,4-imino-D-glucitol 
• 117781-09-6 N-benzyl-1,4-dideoxy-1,4-imino-D-glucitol 

Relevant articles and documents

POLYHYDROXYLATED PYRROLIDINES FROM SUGAR LACTONES: SYNTHESIS OF 1,4-DIDEOXY-1,4-IMINO-D-GLUCITOL FROM D-GALACTONOLACTONE AND SYNTHESES OF 1,4-DIDEOXY-1,4-IMINO-D-ALLITOL, 1,4-DIDEOXY-1,4-IMINO-D-RIBITOL, AND (2S,3R,4S)-3,4-DIHYDROXYPROLINE FROM D-GULONOLACTONE

The use of readily available sugar lactones in the synthesis of polyhydroxylated pyrrolidines is illustrated by the preparation of the glucosidase inhibitor 1,4-dideoxy-1,4-imino-D-glucitol from D-galactonolactone and by the conversion of D-gulonolactone into 1,4-dideoxy-1,4-imino-D-allitol, 1,4-dideoxy-1,4-imino-D-ribitol, and (2S,3R,4S)-3,4-dihydroxyproline.