1178899-17-6Relevant articles and documents
Structure and Reactivity of N-Heterocyclic Alkynyl Hypervalent Iodine Reagents
Le Du, Eliott,Duhail, Thibaut,Wodrich, Matthew D.,Scopelliti, Rosario,Fadaei-Tirani, Farzaneh,Anselmi, Elsa,Magnier, Emmanuel,Waser, Jerome
, p. 10979 - 10986 (2021)
Ethynylbenziodoxol(on)e (EBX) cyclic hypervalent iodine reagents have become popular reagents for the alkynylation of radicals and nucleophiles, but only offer limited possibilities for further structure and reactivity fine-tuning. Herein, the synthesis o
Merging hypervalent iodine and sulfoximine chemistry: A new electrophilic trifluoromethylation reagent
Kalim, Jorna,Duhail, Thibaut,Le, Thanh-Nghi,Vanthuyne, Nicolas,Anselmi, Elsa,Togni, Antonio,Magnier, Emmanuel
, p. 10516 - 10523 (2019/12/02)
Electrophilic trifluoromethylation is at the forefront of methodologies available for the installation of the CF3 moiety to organic molecules; research in this field is largely spurred by the availability of stable and accessible trifluoromethy
Aromatic and benzylic C-H bond functionalization upon reaction between nitriles and perfluoroalkyl sulfoxides
Mace, Yohan,Urban, Celine,Pradet, Charlotte,Blazejewski, Jean-Claude,Magnier, Emmanuel
supporting information; experimental part, p. 5313 - 5316 (2010/02/27)
We studied the thermal behavior of some intermediates formed by reaction of nitriles with perfluoroalkyl sulfoxides upon trifluoromethanesulfonic anhydride activation. Bistriflate ketal 3, precursor of sulfilimine 1, may undergo a rearrangement to sulfany