95414-68-9Relevant articles and documents
Photoredox-Initiated 1,2-Difunctionalization of Alkenes with N-Chloro S-Fluoroalkyl Sulfoximines
Prieto, Alexis,Diter, Patrick,Toffano, Martial,Hannedouche, Jér?me,Magnier, Emmanuel
, p. 436 - 440 (2019)
We describe herein the photoredox-initiated 1,2-difunctionalization of alkene derivatives with N-chloro S-fluoroalkyl sulfoximines yielding novel fluoroalkyl sulfoximine scaffolds. The reaction is proposed to proceed through an atom-transfer radical addition (ATRA) mechanism involving the generation of fluorinated nitrogen-centered sulfoximidoyl radicals. (Figure presented.).
Structure and Reactivity of N-Heterocyclic Alkynyl Hypervalent Iodine Reagents
Le Du, Eliott,Duhail, Thibaut,Wodrich, Matthew D.,Scopelliti, Rosario,Fadaei-Tirani, Farzaneh,Anselmi, Elsa,Magnier, Emmanuel,Waser, Jerome
supporting information, p. 10979 - 10986 (2021/06/08)
Ethynylbenziodoxol(on)e (EBX) cyclic hypervalent iodine reagents have become popular reagents for the alkynylation of radicals and nucleophiles, but only offer limited possibilities for further structure and reactivity fine-tuning. Herein, the synthesis o
Optimization and Gram-Scale Preparation of S-Trifluoromethyl Sulfoximines and Sulfilimino Iminiums, Powerful Reagents for the Late Stage Introduction of the CF3 Group
Barthelemy, Anne-Laure,Certal, Victor,Dagousset, Guillaume,Anselmi, Elsa,Bertin, Luc,Fabien, Laurence,Salgues, Bruno,Courtes, Philippe,Poma, Christian,El-Ahmad, Youssef,Magnier, Emmanuel
, p. 704 - 712 (2019/11/19)
S-Trifluoromethyl sulfoximines and S-trifluoromethyl sulfilimino iminiums are important reagents for the electrophilic or radical late-stage introduction of the CF3 group. We disclose in this article a reappraisal of our previous methodologies
