1178899-38-1Relevant articles and documents
Optimization and Gram-Scale Preparation of S-Trifluoromethyl Sulfoximines and Sulfilimino Iminiums, Powerful Reagents for the Late Stage Introduction of the CF3 Group
Barthelemy, Anne-Laure,Certal, Victor,Dagousset, Guillaume,Anselmi, Elsa,Bertin, Luc,Fabien, Laurence,Salgues, Bruno,Courtes, Philippe,Poma, Christian,El-Ahmad, Youssef,Magnier, Emmanuel
, p. 704 - 712 (2019/11/19)
S-Trifluoromethyl sulfoximines and S-trifluoromethyl sulfilimino iminiums are important reagents for the electrophilic or radical late-stage introduction of the CF3 group. We disclose in this article a reappraisal of our previous methodologies
Functionalized S-perfluorinated sulfoximines: Preparation and evaluation in catalytic processes
Le, Thanh-Nghi,Diter, Patrick,Pégot, Bruce,Bournaud, Chloée,Toffano, Martial,Guillot, Regis,Vo-Thanh, Giang,Yagupolskii, Yurii,Magnier, Emmanuel
, p. 179 - 187 (2015/11/10)
N-substituted S-perfluoroalkylated sulfoximines were synthesized from the NH sulfoximines either by a copper coupling reaction with aryl halides or by a reaction with electrophilic substrates. The procedure allowed the preparation of N,N′-bridged bis sulf
Sulfoximines as a versatile scaffold for electrophilic fluoroalkylating reagents
Urban, Celine,Cadoret, Frederic,Blazejewski, Jean-Claude,Magnier, Emmanuel
experimental part, p. 4862 - 4867 (2011/10/09)
New electrophilic fluoroalkylating agents based on the sulfoximine skeleton as a common platform are described. We demonstrate the importance of the activating group, attached to the nitrogen, and its specificity for the fluorinated group to be delivered.
