117890-58-1

Basic information

• Product Name: 4-(bromomethyl)-1-chloro-2-methylbenzene
• Synonyms: 4-(bromomethyl)-1-chloro-2-methylbenzene
• CAS NO: 117890-58-1
• Molecular Weight: 219.509
• Mol File: 117890-58-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-(bromomethyl)-1-chloro-2-methylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(bromomethyl)-1-chloro-2-methylbenzene(117890-58-1)
• EPA Substance Registry System: 4-(bromomethyl)-1-chloro-2-methylbenzene(117890-58-1)

Safety Data

• Hazardous Substances Data: 117890-58-1(Hazardous Substances Data)

Upstream product

• 131271-19-7 4-chloro-3-methylbenzyl alcohol 
• 7697-29-2 4-chloro-3-methylbenzoic acid 
• 95-66-9 2,4-dimethylchlorobenzene 

Downstream Products

• 1251529-10-8 C₁₉H₂₅ClN₂O₃ 
• 1251529-07-3 1-(4-chloro-3-methyl-benzyl)-piperidin-4-one 
• 1372127-17-7 C₁₈H₁₄O₈*C₂₇H₃₄ClN₅O₃ 
• 1251528-23-0 C₂₇H₃₄ClN₅O₃ 
• 1251527-67-9 C₂₆H₃₁ClN₄O₄ 
• 1251527-64-6 C₂₆H₃₁ClN₄O₄ 
• 1251529-11-9 1-[1-(4-chloro-3-methyl-benzyl)-piperidin-4-yl]-5-oxo-pyrrolidine-2-carboxylic acid 
• 1251529-09-5 C₁₉H₂₇ClN₂O₄ 
• 1251529-08-4 C₂₃H₃₅ClN₂O₄ 
• 1262727-25-2 diethyl 4-chloro-3-methylbenzylphosphonate 
• 1251529-18-6 C₁₇H₂₁ClN₂O₄*ClH 
• 106272-03-1 (4-chloro-3-methyl-phenyl)-cyclohex-1-enyl ketone 
• 21900-24-3 3-methyl-4-chloro benzoylchloride 
• 122488-84-0 6-Chloro-9-(4-chloro-3-methyl-benzyl)-2-trifluoromethyl-9H-purine 

Relevant articles and documents

Steric effects of the initiator substituent position on the externally initiated polymerization of 2-bromo-5-iodo-3-hexylthiophene

Externally initiated polymerization of 2-bromo-3-hexyl-5-iodothiophene was attempted from four aryl and thiophene based small molecule initiators functionalized with a phosphonate moiety. Initiated poly(3-hexylthiophene) product was obtained in various yields depending on the nature of the initiating molecule. Reaction intermediates for the oxidative addition and the ligand exchange steps were analyzed utilizing both experimental and theoretical methods. It was observed that an ortho substituent plays a crucial role in the outcome of the polymerization mechanism and that aryl based initiators are generally more stable than thiophene based initiators. Density functional theory (DFT) calculations revealed the importance of the steric effects on the success of the externally initiated chain growth polymerization mechanism.