118063-60-8

Basic information

• Product Name: (1S)-<1-²H> N-t-butyloxycarbonyl 4-methoxybenzylamine
• CAS NO: 118063-60-8
• Molecular Weight: 238.291
• Mol File: 118063-60-8.mol

Chemical Properties

• CAS DataBase Reference: (1S)-<1-²H> N-t-butyloxycarbonyl 4-methoxybenzylamine(CAS DataBase Reference)
• NIST Chemistry Reference: (1S)-<1-²H> N-t-butyloxycarbonyl 4-methoxybenzylamine(118063-60-8)
• EPA Substance Registry System: (1S)-<1-²H> N-t-butyloxycarbonyl 4-methoxybenzylamine(118063-60-8)

Safety Data

• Hazardous Substances Data: 118063-60-8(Hazardous Substances Data)

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 
• 118063-61-9 N-phthaloyl (1S)-<1-²H>-4-methoxybenzylamine 
• 123-11-5 4-methoxy-benzaldehyde 
• 124176-47-2 (1R)-<1-²H>-4-methoxybenzylalcohol 
• 15190-13-3 (4-methoxy-phenyl)-morpholin-4-yl-acetonitrile 
• 19486-71-6 p-methoxybenzaldehyde-d1 
• 39508-36-6 1-<²H>-1-(4-methoxyphenyl)-1-morpholinoacetonitrile 

Relevant articles and documents

A Practical Large Scale Chemical Synthesis of Chiral Glycines

(R)- and (S)-2H>glycine of high chiral purity were synthesized in large quantities in ca.40percent overall yield from readily available starting materials via a totally chemical procedure.Reduction of either 2H>-furfural or 2H>-4-methoxybenzaldehyde with either (+) or (-)-B-isopinocampheyl-9-borabicyclononane gave chiral arylmethyl alcohols which were converted into their respective phthaloyl amino derivatives of the opposite configuration at the methylene carbon via the Mitsunobu reaction.The aromatic groups were oxidatively unmasked to give their corresponding glycine derivatives by either ozone or ruthenium tetraoxide oxidation.