118495-07-1

Basic information

• Product Name: 7-(BENZYLOXY)-2-NAPHTHOL
• Synonyms: 7-(BENZYLOXY)-2-NAPHTHOL
• CAS NO: 118495-07-1
• Molecular Formula: C₁₇H₁₄O₂
• Molecular Weight: 250.29
• Mol File: 118495-07-1.mol
• Article Data: 13

Chemical Properties

• Melting Point: 151-152°C
• Boiling Point: 444.1°Cat760mmHg
• Flash Point: 279.2°C
• Appearance: /
• Density: 1.21g/cm³
• Vapor Pressure: 1.68E-08mmHg at 25°C
• Refractive Index: 1.669
• CAS DataBase Reference: 7-(BENZYLOXY)-2-NAPHTHOL(CAS DataBase Reference)
• NIST Chemistry Reference: 7-(BENZYLOXY)-2-NAPHTHOL(118495-07-1)
• EPA Substance Registry System: 7-(BENZYLOXY)-2-NAPHTHOL(118495-07-1)

Safety Data

• HazardClass: IRRITANT
• Hazardous Substances Data: 118495-07-1(Hazardous Substances Data)

Usage

General Description

"7-(Benzyloxy)-2-naphthol" is a chemical compound that generally belongs to the class of organic compounds known as 1-benzyl-2-naphthols. These are aromatic compounds containing a 2-naphthol substituted at the C1 position by a benzyl group. Its systematic name is "7-(Benzyloxy)naphthalen-2-ol". As a scientific reagent, it is often used in a variety of complex organic syntheses. Specific information about its other intrinsic properties such as boiling point, melting point, density, solubility, and chemical structure largely depends on the conditions under which it is stored and used.

InChI:InChI=1/C17H14O2/c18-16-8-6-14-7-9-17(11-15(14)10-16)19-12-13-4-2-1-3-5-13/h1-11,18H,12H2

Upstream product

• 582-17-2 2,7-Dihydroxynaphthalene 
• 146744-23-2 2-acetoxy-7-hydroxynaphthalene 
• 1257230-84-4 2-acetoxy-7-benzyloxynaphthalene 
• 100-39-0 benzyl bromide 
• 100-44-7 benzyl chloride 

Downstream Products

• 1122065-29-5 7-(benzyloxy)naphthalen-2-yl pivalate 
• 1122065-43-3 2-(benzyloxy)-7-phenylnaphthalene 
• 1398119-44-2 C₃₃H₂₄O₄ 

Relevant articles and documents

Organocatalytic Enantioselective Synthesis of Atropisomeric Aryl-p-Quinones: Platform Molecules for Diversity-Oriented Synthesis of Biaryldiols

Presented here is a class of novel axially chiral aryl-p-quinones as platform molecules for the preparation of non-C2 symmetric biaryldiols. Two sets of aryl-p-quinone frameworks were synthesized with remarkable enantiocontrol by means of chiral phosphoric acid catalyzed enantioselective arylation of p-quinones by central-to-axial chirality conversion. These aryl-p-quinones were then used to access a wide spectrum of highly functionalized non-C2 symmetric biaryldiols with excellent retention of the enantiopurity.

Lewis Acid-Mediated Cyanation of Phenols Using N-Cyano-N-phenyl-p-toluenesulfonamide

Lewis acid-mediated cyanation of phenol derivatives with N-cyano-N-phenyl-p-toluenesulfonamide (NCTS) has been developed. The reaction proceeded efficiently with high regioselectivity to produce aromatic nitriles in moderate to excellent yields, which provides a direct and practical access to valuable products. (Figure presented.).

A novel molecular cleft based on dioxocin ring, part I: Synthesis and conformational analysis

The Molecular cleft 1 using 8-methyl-16H-dinaphtho[2,1-d:1,2-g][1,3]dioxocin-2,14-diol as a spacer was synthesized. Density functional calculations at B3LYP/6-31G level of theory indicates that 8-methyl-16H-dinaphtho[2,1-d:1,2-g][1,3]dioxocin, the central