1186200-29-2

Basic information

• Product Name: 2-[(2-benzoyloxy-4-fluoro)phenyl]pyridine
• Synonyms: 2-[(2-benzoyloxy-4-fluoro)phenyl]pyridine
• CAS NO: 1186200-29-2
• Molecular Weight: 293.297
• Mol File: 1186200-29-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-[(2-benzoyloxy-4-fluoro)phenyl]pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(2-benzoyloxy-4-fluoro)phenyl]pyridine(1186200-29-2)
• EPA Substance Registry System: 2-[(2-benzoyloxy-4-fluoro)phenyl]pyridine(1186200-29-2)

Safety Data

• Hazardous Substances Data: 1186200-29-2(Hazardous Substances Data)

Upstream product

• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 109-04-6 2-bromo-pyridine 
• 1765-93-1 4-fluoroboronic acid 
• 58861-53-3 4-fluorophenylpyridine 
• 6597-18-8 (dibenzoyloxyiodo)benzene 
• 65-85-0 benzoic acid 

Relevant articles and documents

Palladium catalyzed ortho-C-H-benzoxylation of 2-arylpyridines using iodobenzene dibenzoates

A palladium-catalyzed ortho-C-H-benzoxylation of 2-arylpyridines using iodobenzene dibenzoates has been developed. The reaction employed the stable and easily accessible hypervalent iodine reagents as both benzoxylate source and oxidant which made the protocol simple and facile. It showed high regioselectivity and good functional group tolerance, and gave the mono-benzoxylation products in moderate to excellent yields.

Rhodium-catalyzed ortho-benzoxylation of sp2 C-H bond

Figure Presented A rhodium-catalyzed ortho-benzoxylation of the sp 2 C-H bond by carboxylic acids is described. The procedure tolerates carbomethoxy, formyl, bromo, chloro, and nitro groups, providing the benzoxylated products in moderate to good yields. Importantly, no external oxidant was required for the transformation.