119046-50-3

Upstream product

• 19790-60-4 3-Benzyloxypropanal 
• 58207-97-9 tributyl[(E)-2-trimethylsilylethenyl]stannane 
• 55339-31-6 lithium 
• 88191-39-3 (Z)-((hex-3-en-1-yloxy)-methyl)benzene 
• 100-39-0 benzyl bromide 

Downstream Products

• 119046-52-5 (S)-3-Benzyloxy-1-((2S,3S)-3-trimethylsilanyl-oxiranyl)-propan-1-ol 
• 119180-88-0 (E)-(R)-5-Benzyloxy-1-trimethylsilanyl-pent-1-en-3-ol 
• 120505-32-0 (S)-2-[(R)-3-Benzyloxy-1-(1-methoxy-1-methyl-ethoxy)-propyl]-oxirane 
• 120505-31-9 (R)-2-[(S)-3-Benzyloxy-1-(1-methoxy-1-methyl-ethoxy)-propyl]-oxirane 
• 117661-29-7 (R)-5-(benzyloxy)pent-1-en-3-ol 
• 117661-29-7 (3S)-3-hydroxy-5-benzyloxy-1-pentene 

Relevant academic research and scientific papers

A HIGHLY EFFICIENT KINETIC RESOLUTION OF γ- AND β-TRIMETHYLSILYL SECONDARY ALLYLIC ALCOHOLS BY THE SHARPLESS ASYMMETRIC EPOXIDATION

Kinetic resolution of γ- and β-trimethylsilyl secondary allylic alcohols proceeds with very large and synthetically satisfactory rate differences for the two enentiomers, respectively, thus providing a convenient and widely applicable method for preparati

A Practical Synthesis of Several Polyhydroxylated Chiral Building Blocks

A practical method for the synthesis of several useful polyhydroxylated chiral building blocks has been developed.The key reaction is the kinetic resolution of (E)-1-trimethylsilyl-4-alkoxy-1-buten-3-ol or (E)-1-trimethylsilyl-5-alkoxy-1-penten-3-ol using the Sharpless asymmetric epoxidation reaction.