119125-16-5

Basic information

• Product Name: phenyl 4,6-O-benzylidene-2-deoxy-3-O-methyl-2-C-p-tolylsulfonyl-α-D-glucopyranosie
• CAS NO: 119125-16-5
• Molecular Weight: 496.581
• Mol File: 119125-16-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: phenyl 4,6-O-benzylidene-2-deoxy-3-O-methyl-2-C-p-tolylsulfonyl-α-D-glucopyranosie(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 4,6-O-benzylidene-2-deoxy-3-O-methyl-2-C-p-tolylsulfonyl-α-D-glucopyranosie(119125-16-5)
• EPA Substance Registry System: phenyl 4,6-O-benzylidene-2-deoxy-3-O-methyl-2-C-p-tolylsulfonyl-α-D-glucopyranosie(119125-16-5)

Safety Data

• Hazardous Substances Data: 119125-16-5(Hazardous Substances Data)

Upstream product

• 824-79-3 sodium 4-methylbenzenesulfinate 
• 119125-08-5 phenyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-α-D-erythro-hex-2-enopyranoside 
• 1464-44-4 phenyl α-D-mannoopyranoside 
• 119125-09-6 phenyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-2-C-p-tolylsulfonyl-α-D-mannopyranoside 
• 100-52-7 benzaldehyde 
• 67-56-1 methanol 
• 119125-05-2 phenyl 4,6-O-benzylidene-2,3-dideoxy-2-C-p-tolylsulfonyl-α-D-erythro-hex-2-enopyranoside 
• 119125-07-4 phenyl 4,6-O-benzylidene-3-deoxy-3-C-nitro-α-D-glucopyranoside 

Relevant articles and documents

REACTIONS OF METHYL 4,6-O-BENZYLIDENE-2,3-DIDEOXY-2-C-p-TOLYLSULFONYL-α-D-erythro-HEX-2-ENOPYRANOSIDE AND ITS PHENYL ANALOGUE WITH SODIUM METHOXIDE

Reaction of the title methyl glycoside 5 with methanolic sodium methoxide afforded mainly the isomeric α-D-erythro-hex-3-enopyranoside derivative 13, formed by migration of the double bond from C-2 to C-3, together with 1,5-anhydro-4,6-O-benzylidene-2-deo