223392-45-8

Upstream product

• 1519-39-7 (R)-methyl p-tolyl sulfoxide 

Downstream Products

• 116386-56-2 (7R,8R)-8-Chloro-2-methyl-8-((R)-toluene-4-sulfinyl)-octadecan-7-ol 
• 116498-90-9 (7S,8R)-8-Chloro-2-methyl-8-((R)-toluene-4-sulfinyl)-octadecan-7-ol 
• 223392-49-2 (2R,3S)-2-Decyl-3-phenyl-2-((R)-toluene-4-sulfinyl)-oxirane 
• 223392-50-5 (2R,3R)-2-Decyl-3-phenyl-2-((R)-toluene-4-sulfinyl)-oxirane 
• 119487-96-6 (2R,3R)-2-Decyl-1,3-diphenyl-2-((S)-toluene-4-sulfinyl)-aziridine 
• 223392-51-6 (2S,3S)-2-Decyl-3-phenyl-oxirane-2-carboxylic acid ethyl ester 
• 223392-52-7 (2S,3R)-2-Decyl-3-phenyl-oxirane-2-carboxylic acid ethyl ester 
• 54910-51-9 (2S-cis)-7,8-epoxy-2-methyloctadecane 
• 116386-57-3 (2R,3S)-2-Decyl-3-(5-methyl-hexyl)-2-(toluene-4-sulfinyl)-oxirane 
• 116386-57-3 (2R,3R)-2-Decyl-3-(5-methyl-hexyl)-2-(toluene-4-sulfinyl)-oxirane 
• 302354-75-2 (2R,3R)-2-Decyl-2-(3-methoxy-benzyl)-1,3-diphenyl-aziridine 

Relevant academic research and scientific papers

THE PRACTICAL PROCEDURE FOR A PREPARATION OF 1-CHLOROALKYL p-TOLYL SULFOXIDES IN HIGH OPTICALLY ACTIVE FORM: A VERY SHORT SYNTHESIS OF OPTICALLY ACTIVE DISPARLURE

A chlorination of optically active alkyl p-tolyl sulfoxides with N-chlorosuccinimide in dichloromethane in the presence of potassium carbonate afforded optically active 1-chloroalkyl p-tolyl sulfoxides in 87-94percent ee (88-94percent chemical yields).The optically active chloroalkyl sulfoxide was applied to a synthesis of optically active (+)-disparlure.