1195-98-8Relevant articles and documents
Bunnett, Brotherton
, p. 904 (1958)
Oxidative nucleophilic substitution of hydrogen in nitrobenzene with 2-phenylpropionitrile carbanion and potassium permanganate oxidant
Makosza, Mieczyslaw,Stalinski, Krzysztof,Klepka, Cezary
, p. 837 - 838 (1996)
The carbanion of 2-phenylpropionitrile adds to nitrobenzene in the p-position in liquid ammonia to give the relative stable σH-adduct which is oxidised with KMnO4 to 2-phenyl-2-(4-nitrophenyl)propionitrile; the relationships of rates of various reactions in these systems are estimated.
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Semmelhack et al.
, p. 1247 (1975)
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Preparation of tertiary benzylic nitriles from aryl fluorides [1]
Caron, Stephane,Vazquez, Enrique,Wojcik, Jill M.
, p. 712 - 713 (2000)
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Selvarajan,Boyer
, p. 889 (1970)
Palladium-Catalyzed Distal m-C-H Functionalization of Arylacetic Acid Derivatives
Srinivas, Dasari,Satyanarayana, Gedu
supporting information, p. 7353 - 7358 (2021/10/01)
Herein, we present m-C-H olefination on derivatives of phenylacetic acids by tethering with a simple nitrile-based template through palladium catalysis. Notably, the versatility of the method is evaluated with a wide range of phenylacetic acid derivatives for obtaining the meta-olefination products in fair to excellent yields with outstanding selectivities under mild conditions. Significantly, the present strategy is successfully exemplified for the synthesis of drugs/natural product analogues (naproxen, ibuprofen, paracetamol, and cholesterol).
Luminescent tungsten(vi) complexes as photocatalysts for light-driven C-C and C-B bond formation reactions
Chan, Kaai-Tung,Che, Chi-Ming,Du, Lili,Liu, Yungen,Phillips, David Lee,To, Wai-Pong,Tong, Glenna So Ming,Wu, Liang-Liang,Yu, Daohong
, p. 6370 - 6382 (2020/07/15)
The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(vi) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C-C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance.
Oxidation of aldehydes to nitriles with an oxoammonium salt: Preparation of piperonylonitrile
Kaetzel, Nathaniel D.,Kelly, Christopher B.,Lambert, Kyle M.
, p. 294 - 313 (2020/11/09)
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