17988-38-4Relevant academic research and scientific papers
Strategic Trimethylsilyldiazomethane Insertion into pinB-SR Followed by Selective Alkylations
Civit, Marc G.,Royes, Jordi,Vogels, Christopher M.,Westcott, Stephen A.,Cuenca, Ana B.,Fernández, Elena
supporting information, p. 3830 - 3833 (2016/08/16)
The insertion of the diazo derivative Me3SiCHN2 into pinB-SR σ bonds (R = Ph, Tol, Bn) allows a direct synthesis of multisubstituted H-C(SR)(Bpin)(SiMe3) compounds. Consecutive base-assisted transformations of HC(S)(B) (Si
GENERATION OF SULFUR YLIDES BY THE DESILYLATION OF α-TRIMETHYLSILYLBENZYL SULFONIUM SALTS
Padwa, Albert,Gasdaska, John R.
, p. 4147 - 4156 (2007/10/02)
The -sigmatropic rearrangement of sulfur ylides derived via the desilylation of several α-trimethylsilylbenzyl sulfonium salts has been studied.The initally formed ylide was found to rapidly equilibrate with the thermodynamically more stable ylide.In the absence of trapping reagents, a Sommelet-Hauser type rearrangement occurs.
