119612-85-0

Basic information

• Product Name: Silane, [(1-cyclohexylethenyl)oxy]trimethyl-
• CAS NO: 119612-85-0
• Molecular Formula: C11H22OSi
• Molecular Weight: 198.381
• Mol File: 119612-85-0.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Silane, [(1-cyclohexylethenyl)oxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(1-cyclohexylethenyl)oxy]trimethyl-(119612-85-0)
• EPA Substance Registry System: Silane, [(1-cyclohexylethenyl)oxy]trimethyl-(119612-85-0)

Safety Data

• Hazardous Substances Data: 119612-85-0(Hazardous Substances Data)

Upstream product

• 823-76-7 Cyclohexyl methyl ketone 
• 2043-61-0 cyclohexanecarbaldehyde 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 61771-79-7 1-cyclohexylpentane-1,4-dione 
• 797752-69-3 2-(2'-cyclopenten-1'-yl)-1-cyclohexyl-1-oxoethane 
• 139336-65-5 (1-Cyclohexyl-cyclopropoxy)-trimethyl-silane 
• 6004-53-1 1-cyclohexyl-2-hydroxyethanone 
• 695-12-5 vinylcyclohexane 
• 2652-41-7 1,1,1-triethyl-3,3,3-trimethyl-disiloxane 
• 1241391-02-5 N-(2-cyclohexyl-2-oxoethyl)-4-methylbenzenesulfonamide 
• 939377-20-5 ethyl 5-cyclohexyl-2-methylfuran-3-carboxylate 
• 62455-70-3 3-cyclohexyl-3-oxopropanenitrile 
• 155130-53-3 2-Methyl-5-cyclohexyl-6-(methoxymethoxy)-4(Z)-hexenoic acid 
• 155130-68-0 1-(Methoxymethoxy)-2-(propionyloxy)-2-cyclohexyl-4-butene 
• 170450-94-9 1-(Methoxymethoxy)-2-cyclohexyl-3-buten-2-ol 
• 170451-00-0 1-(Methoxymethoxy)methyl cyclohexyl ketone 

Relevant articles and documents

2-(Chlorocarbonyl)-2-mesitylketene, a new building block for the synthesis of 4-hydroxy-3-mesityl tetronic acids

Investigation of the reaction of (chlorocarbonyl)mesitylketene with ketones led to the discovery of a new synthetic pathway which yields 4-hydroxy-3-mesityl tetronic acids. Depending on the reaction conditions and the substitution pattern of the starting ketone, the expected products, i.e. 4-hydroxy-3-mesitylpyrones, can nevertheless be obtained.

Iron-Catalyzed Ring-Opening Reactions of Cyclopropanols with Alkenes and TBHP: Synthesis of 5-Oxo Peroxides

The ring opening of cyclopropanols is rarely used in multicomponent reactions. Herein we report the three-component reaction of cyclopropanols with alkenes and tert-butyl hydroperoxide (TBHP) catalyzed by an iron catalyst. This protocol enables the incorporation of both the β-carbonyl fragment and a peroxy unit across the C=C double bond regioselectively, thus allowing an efficient, facile access to 5-oxo peroxides. Modification of the biologically active molecules and various downstream derivatizations of the peroxides are also demonstrated.

Metal-Free Catalytic Reductive Cleavage of Enol Ethers

In contrast to the well-known reductive cleavage of the alkyl-O bond, the cleavage of the alkenyl-O bond is much more challenging especially using metal-free approaches. Unexpectedly, alkenyl-O bonds were reductively cleaved when enol ethers were reacted with Et3SiH and a catalytic amount of B(C6F5)3. Supposedly, this reaction is the result of a B(C6F5)3-catalyzed tandem hydrosilylation reaction and a silicon-assisted β-elimination. A mechanism for this cleavage reaction is proposed based on experiments and density functional theory (DFT) calculations.