119770-85-3Relevant academic research and scientific papers
A Convenient Synthesis of Pyranoid Ene Lactones from Phenyl Glycosyl Sulfones
Qiu, Dongxu,Schmidt, Richard R.
, p. 875 - 877 (2007/10/02)
O-Benzyl protected pyranoid ene lactones (5,6-dihydro-2H-pyran-2-ones) 4a-c, 8 were obtained in high yield in a two-step procedure.Treatment of the phenyl glycosyl sulfones 2a-d, 6, which were readily prepared from their corresponding sulfides, with lithi
Conjugate addition to chiral γ-heterosubstituted δ-lactones as pivotal synthons from L-glutamic acid. Synthesis of an optically active lignan lactone; (-)-hinokinin
Yoda,Naito,Takabe,Tanaka,Hosoya
, p. 7623 - 7626 (2007/10/02)
Asymmetric induction in conjugate addition of new chiral γ-heterosubstituted-α, β-unsaturated δ-lactones from L-glutamic acid was accomplished in high diastereoselectivity with the formation of trans-(R,S)-adducts and was disclosed to serve as a versatile procedure for the asymmetric synthesis of antileukemic lignan lactones.
