119784-85-9

Upstream product

• 32276-00-9 S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 104-54-1 3-Phenylpropenol 
• 86-93-1 1-Phenyl-1H-tetrazole-5-thiol 

Downstream Products

• 140863-27-0 1,3-diphenyl-1-oxo-4-pentene 
• 28069-36-5 (E)-1,5-diphenylpent-4-en-1-one 
• 3412-44-0 (1E)-1,3-diphenylpropene 
• 58463-02-8 (1E,5E)-1,6-diphenyl-1,5-hexadiene 
• 16215-11-5 trans-cinnamyl p-tolyl sulfone 
• 119793-72-5 (E)-2-(3-phenyl-allyl) malonic acid dimethyl ester 
• 119784-73-5 dimethyl bis<(E)-3-phenyl-2-propenyl>malonate 

Relevant academic research and scientific papers

A direct and efficient preparation of 1-phenyltetrazol-5-yl sulfides from alcohols

Treatment of primary or secondary alcohols with 1-phenyl-1(H)-tetrazole-5- thiol and [Me2NCHSEt]+ BF4- leads directly and cleanly to 1-phenyl-1(H)-tetrazol-5-yl sulfides.

SINGLE-STEP PREPARATION OF ALLYLIC SULFIDES HAVING 1-PHENYLTETRAZOLE-5-THIO GROUP FROM ALLYLIC ALCOHOLS USING S,S'-BIS(1-PHENYL-1H-TETRAZOL-5-YL) DITHIOCARBONATE AND REACTIONS INVOLVING THE ALLYLIC SULFIDES

The reaction of allylic alcohols and S,S'-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate (1) gave allylic sulfides having 1-phenyltetrazole-5-thio group in a single step.Furthermore, these allylic sulfides could be applied to carbon-carbon bond and carbon-sulfur bond formations by using Grignard reagents or carbanions in the presence of catalytic amount of copper(I) bromide or palladium (0), respectively.