1199-46-8

Basic information

• Product Name: 2-Amino-4-tert-butylphenol
• Synonyms: 2-AMINO-4-T-BUTYLPHENOL;2-AMINO-4-TERT-BUTYLPHENOL;2-HYDROXY-5-TERT-BUTYLANILINE;T-BUTYL-O-AMINOPHENOL;o-Amino-p-tert-butylphenol;2-Amino-4-tert-Butylphenol 1199-46-8;p-tert-Butyl-o-aminophenol;2-AMINO- 4-TERT. BUTYL PHENOL 97+%
• CAS NO: 1199-46-8
• Molecular Formula: C₁₀H₁₅NO
• Molecular Weight: 165.23
• EINECS: 214-844-4
• Product Categories: Industrial/Fine Chemicals;Aromatic Phenols;Phenoles and thiophenoles;Acetone series;Organic Building Blocks;Oxygen Compounds;Phenols
• Mol File: 1199-46-8.mol
• Article Data: 15

Chemical Properties

• Melting Point: 160-163 °C(lit.)
• Boiling Point: 293.09°C (rough estimate)
• Flash Point: 120.1 ºC
• Appearance: white crystals
• Density: 1.0203 (rough estimate)
• Vapor Pressure: 0.00313mmHg at 25°C
• Refractive Index: 1.5290 (estimate)
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• PKA: 9.97±0.18(Predicted)
• CAS DataBase Reference: 2-Amino-4-tert-butylphenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Amino-4-tert-butylphenol(1199-46-8)
• EPA Substance Registry System: 2-Amino-4-tert-butylphenol(1199-46-8)

Safety Data

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• Hazardous Substances Data: 1199-46-8(Hazardous Substances Data)

Usage

Chemical Properties

BEIGE TO BROWN CRYSTALLINE POWDER

Uses

2-Amino-4-tert-butylphenol can be used as a reactant to prepare: 4-tert-butyl-2-[(pyridylmethylene)amino]phenol intermediates, which are used to synthesize biologically important 2-(pyridyl)benzoxazole derivatives.Prolinamide phenols, as efficient hydrophobic organocatalysts for direct asymmetric aldol reaction aldehydes and ketones in water.N-(2-hydroxy-4-tert-butylphenyl)-acetamide, a key intermediate to prepare uranylsalophene derivatives which can be used as selective receptors in anion sensitive membrane sensors.Poly(2-amino-4-tert-butylphenol) [poly(2A-4TBP)] by electrochemical or chemical oxidative polymerization reaction.

InChI:InChI=1/C10H15NO/c1-10(2,3)7-4-5-9(12)8(11)6-7/h4-6,12H,11H2,1-3H3

Upstream product

• 15331-61-0 4-tert-Butyl-2-phenylazo-phenol 
• 3279-07-0 4-tert-butyl-2-nitrophenol 
• 98-54-4 para-tert-butylphenol 
• 100-34-5 benzene diazonium chloride 
• 7440-44-0 pyrographite 
• 1129-21-1 4-t-butyl-1,2-benzoquinone 
• 100-46-9 benzylamine 

Downstream Products

• 40874-54-2 5-(tert-butyl)-2-methylbenzo[d]oxazole 
• 25847-91-0 1-(5-tert-Butyl-2-hydroxy-phenyl)-3-phenyl-urea 
• 25761-44-8 1-(5-tert-Butyl-2-hydroxy-phenyl)-3-(4-chloro-3-trifluoromethyl-phenyl)-urea 
• 22510-44-7 N-(5-tert-Butyl-2-hydroxy-phenyl)-N'-phenyl-oxalamide 
• 22510-48-1 N-(5-tert-Butyl-2-hydroxy-phenyl)-N'-(4-ethoxy-phenyl)-oxalamide 
• 22486-26-6 N-(5-tert-Butyl-2-hydroxy-phenyl)-N'-p-tolyl-oxalamide 
• 25761-29-9 1-(5-tert-Butyl-2-hydroxy-phenyl)-3-(3,4-dichloro-phenyl)-urea 
• 34174-29-3 N-(3-(trifluoromethyl)phenyl)-N'-(2-hydroxy-5-tert-butylphenyl)-urea 
• 25790-99-2 1-(5-tert-Butyl-2-hydroxy-phenyl)-3-(3-chloro-4-trifluoromethyl-phenyl)-urea 
• 6529-93-7 4-tert-butyl-2-(2-chloro-acetylamino)-phenol 
• 106404-88-0 N,N'-di-(2-hydroxy-5-tert-butylphenyl)oxalamide 
• 53146-48-8 5-(tert-butyl)benzo[d]oxazole-2-thiol 
• 479668-80-9 N-(2-hydroxy-5-t-butylphenyl)-5-bromofuran-2-carboxamide 
• 921198-82-5 N-(5-tert-butyl-2-hydroxyphenyl)-4-nitrobenzamide 

Relevant articles and documents

Record-high catalytic hydrogenated activity in nitroarenes reduction derived from in-situ nascent active metals enabled by constructing bimetallic phosphate

Herein, we report an excellent in-situ exsolution triggered hydrogenated catalyst F-Ni/Cu-P-RT started from bimetallic phosphate Ni/Cu-P-RT, affording an ultrafast catalytic hydrogenated rate (20 s even 5 s) in nitrophenol reduction. In the first catalytic cycle, we proved the enhanced catalytic reduction activity of bimetallic Ni/Cu-P-RT within 50 s compared to monometallic counterparts. The kinetics results revealed Ni/Cu-P-RT affords the reaction rate K of 2.85/4.23/6.6 min?1 at 20, 30, and 40 °C with the activation energy 32 kJ/mol. Impressively, the involved reaction induction period is visibly observed and interpreted by reconstruction and evolution of active metal during the reaction, but was eliminated through integrating two metal Cu-Ni by regulation of electronic band energy of phosphate from 4.1–3.5 eV. The nascent Cu and Ni nanoparticles as reaction-preferred active species were in-situ exsolved partially after adding NaBH4, triggering the resulted higher active and stable F-Ni/Cu-P-RT(20 s, 14.1 min?1) in later multiple cycles.

HARMFUL ARTHROPOD CONTROL COMPOSITION, AND FUSED HETEROCYCLIC COMPOUND

Disclosed is a harmful arthropod control composition comprising, as an active ingredient, a fused heterocyclic compound represented by formula (1) [wherein A1 and A2 independently represent a nitrogen atom or the like; R1 and R4 independently represent a halogen atom or the like; R2 and R3 independently represent a halogen atom or the like; R5 and R6 independently represent a linear C1-C6 hydrocarbon group which may be substituted, or the like (provided that both R5 and R6 cannot represent a hydrogen atom simultaneously); and n represents 0 or 1]. The harmful arthropod control composition has an excellent efficacy to control harmful arthropods.

COMPOSITION AND METHOD FOR CONTROLLING ARTHROPOD PESTS

The present invention provides: an arthropod pests control composition comprising, as active ingredients, a condensed heterocyclic compound and a neonicotinoid compound; a method for controlling arthropod pests which comprises applying effective amounts of a condensed heterocyclic compound and a neonicotinoid compound to the arthropod pests or a locus where the arthropod pests inhabit; and so on.