1201594-37-7

Basic information

• Product Name: (4-[trifluoromethyl]phenyl) N,N-dimethylsulfamate
• Synonyms: (4-[trifluoromethyl]phenyl) N,N-dimethylsulfamate
• CAS NO: 1201594-37-7
• Molecular Weight: 269.245
• Mol File: 1201594-37-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (4-[trifluoromethyl]phenyl) N,N-dimethylsulfamate(CAS DataBase Reference)
• NIST Chemistry Reference: (4-[trifluoromethyl]phenyl) N,N-dimethylsulfamate(1201594-37-7)
• EPA Substance Registry System: (4-[trifluoromethyl]phenyl) N,N-dimethylsulfamate(1201594-37-7)

Safety Data

• Hazardous Substances Data: 1201594-37-7(Hazardous Substances Data)

Upstream product

• 402-45-9 4-hydroxybenzotrifluoride 
• 13360-57-1 dimethylamino sulfonyl chloride 

Downstream Products

• 113845-68-4 1-(4(-trifluoromethyl)phenyl)pyrrolidine 
• 113845-69-5 4-(4-trifluoromethylphenyl)morpholine 
• 1282034-12-1 N-butyl-N-methyl-4-(trifluoromethyl)benzenamine 
• 1264670-40-7 tert-butyl (4-(trifluoromethyl)benzyl)carbamate 
• 1396516-73-6 tert-butyl butyl{4-(trifluoromethyl)benzyl}carbamate 
• 15106-88-4 di(p-tolyl)zinc 
• 97067-18-0 4'-methyl-4-trifluoromethyl-biphenyl 
• 581-80-6 4,4'-bis(trifluoromethyl)biphenyl 
• 134384-31-9 2-(4-trifluoromethylphenyl)benzothiazole 
• 25371-98-6 N-(4-trifluoromethylphenyl)imidazole 

Relevant articles and documents

N -Arylation of (hetero)arylamines using aryl sulfamates and carbamates via C-O bond activation enabled by a reusable and durable nickel(0) catalyst

An effective and general aryl amination protocol has been developed using a magnetically recoverable Ni(0) based nanocatalyst. This new stable catalyst was prepared on Fe3O4@SiO2 modified by EDTA and investigated by FT-IR, EDX, TEM, XRD, DLS, FE-SEM, XPS, NMR, TGA, VSM, ICP and elemental analysis techniques. The reaction proceeded via carbon-oxygen bond cleavage of (hetero)aryl carbamates and sulfamates under simple and mild conditions without the use of any external ligands. This method demonstrated functional group tolerance in the N-arylation of various nitrogen-containing compounds as well as aliphatic amines, anilines, pyrroles, pyrazoles, imidazoles, indoles, and indazoles with good to excellent yields. Furthermore, the catalyst could be easily recovered by using an external magnetic field and directly reused at least six times without notable reduction in its activity. This journal is

Oxidative Addition of Aryl Electrophiles to a Prototypical Nickel(0) Complex: Mechanism and Structure/Reactivity Relationships

Detailed kinetic studies of the reaction of a model Ni0 complex with a range of aryl electrophiles have been conducted. The reactions proceed via a fast ligand exchange pre-equilibrium, followed by oxidative addition to produce either [NiIX(dppf)] (and biaryl) or [NiII(Ar)X(dppf)]; the ortho substituent of the aryl halide determines selectivity between these possibilities. A reactivity scale is presented in which a range of substrates is quantitatively ranked in order of the rate at which they undergo oxidative addition. The rate of oxidative addition is loosely correlated to conversion in prototypical cross-coupling reactions. Substrates that lead to NiI products in kinetic experiments produce more homocoupling products under catalytic conditions.