120803-36-3Relevant articles and documents
Classical benzotriazole-mediated α-aminoalkylations of alkynes: Synthesis and characterization of alk-2-yn-1-amines as amphiphilic materials
Idzik, Krzysztof R.,Cabaj, Joanna,Soloducho, Jadwiga,Abdel-Fattah, Ashraf A. A.
, p. 1672 - 1680 (2008/02/13)
Reactions of readily available and stable benzotriazolemethanamines 1a-1, obtained from aldehydes and secondary amines (Scheme 2), gave the expected alk-2-yn-1-amines 3a-t (Scheme 3). The amphiphilic character of the synthesized products was responsible f
The Chemistry of N-Substituted Benzotriazoles. Part 14. Novel Routes to Secondary and Tertiary Amines and to N,N-Disubstituted Hydroxylamines
Katritzky, Alan R.,Yannakopoulou, Konstantina,Lue, Ping,Rasala, Danuta,Urogdi, Laszlo
, p. 225 - 233 (2007/10/02)
Tertiary amines of types R4R3CHNR1R2 (2), (R2CH2)2NR1 (10) and 11, or (R2CH2)3N (12), secondary amines of type (R2CH2)2NH (8), and N,N-disubstituted hydroxylamines of type (R2CH2)2NOH (9), are prepared in high yield by the action of Grignard reagents or sodium borohydride on easily available N,N-dialkyl-N-amines (1) or tris(benzotriazolylmethyl)amine (7), on bis(benzotriazolylmethyl)amines (3), (5), and (6), and on N,N-bis(benzotriazolylmethyl)hydroxylamine (4), respectively.
