120834-16-4Relevant articles and documents
Preparation of Protected β-Keto Aldehydes from β-Keto Esters via Selective Reduction of Acyl(alkoxycarbonyl)ketene Dithioacetals
Choi, Eun Bok,Youn, In Kwon,Pak, Chwang Siek
, p. 792 - 794 (2007/10/02)
The acyl(alkoxycarbonyl)ketene dithioacetals 2 prepared from the corresponding β-keto esters 1 in almost quantitative yield are reduced selectively with magnesium in methanol and subsequently dealkoxycarbonylated to give protected β-keto aldehydes 4 in hi