121349-49-3Relevant academic research and scientific papers
ELECTRO-INITIATED CYCLOADDITION OF MOLECULAR OXYGEN, OLEFIN, AND 1,3-DIKETONE
Yoshida, Jun-ichi,Sakaguchi, Kazuhiko,Isoe, Sachihiko,Hirotsu, Ken
, p. 667 - 670 (1987)
Electrochemical oxidation of 1,3-diketones in the presence of olefins under an atmosphere of oxygen gave the formal cycloadducts, i.e. cyclic peroxides.A catalytic amount of electricity was sufficient for the reaction and an electro-initiated radi
Formal Cycloaddition of Molecular Oxygen, 1,3-Diketone, and Olefin. Synthesis and Reactions of Cyclic Peroxides
Yoshida, Jun-ichi,Nakatani, Shogo,Sakaguchi, Kazuhiko,Isoe, Sachihiko
, p. 3383 - 3389 (2007/10/02)
Formal cycloaddition of molecular oxygen, 1,3-diketones, and olefins took place by electrochemical oxidation.A catalytic amount of electricity was sufficient for the reaction, and an electroinitiated radical chain mechanism was proposed.The reaction was also initiated by a radical initiator.The resulting cyclic peroxides reacted with acids and some reducing agents such as ferrous sulfate, thiurea, and copper(I) chloride to give oxygen-oxygen bond cleavage products.
