ELECTRO-INITIATED CYCLOADDITION OF MOLECULAR OXYGEN, OLEFIN, AND 1,3-DIKETONE

DOI: 10.1016/S0040-4039(00)95808-8

Source and publish data:

Tetrahedron Letters p. 667 - 670 (1987)

Update date:2022-08-04

Topics:

Authors:

Yoshida, Jun-ichi

Sakaguchi, Kazuhiko

Isoe, Sachihiko

Hirotsu, Ken

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Article abstract of DOI:10.1016/S0040-4039(00)95808-8

Electrochemical oxidation of 1,3-diketones in the presence of olefins under an atmosphere of oxygen gave the formal <2+2+2> cycloadducts, i.e. cyclic peroxides.A catalytic amount of electricity was sufficient for the reaction and an electro-initiated radi

Full text of DOI:10.1016/S0040-4039(00)95808-8

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