1215209-26-9

Basic information

• Product Name: [Cl₂NN]Cu-NHAd
• Synonyms: [Cl₂NN]Cu-NHAd
• CAS NO: 1215209-26-9
• Molecular Weight: 600.905
• Mol File: 1215209-26-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Cl₂NN]Cu-NHAd(CAS DataBase Reference)
• NIST Chemistry Reference: [Cl₂NN]Cu-NHAd(1215209-26-9)
• EPA Substance Registry System: [Cl₂NN]Cu-NHAd(1215209-26-9)

Safety Data

• Hazardous Substances Data: 1215209-26-9(Hazardous Substances Data)

Upstream product

• 1261138-80-0 [(Cu(CH(C(CH3)NC6H3Cl2)2))2(μ-Cl)2] 
• 68295-36-3 lithium adamant-1-ylamide 
• 1215209-38-3 [Cl₂NN]Cu-OtBu 
• 768-94-5 1-Adamantanamine 

Downstream Products

• 768-94-5 1-Adamantanamine 
• 3717-60-0 2-[N-(1-adamantyl)]aminomethylbenzene 
• 57527-54-5 N-(-adamantan-1-yl)-1-phenylmethanimine 
• 1034159-52-8 N-(2,3-dihydro-1H-inden-1-yl)-1-aminoadamantane 
• 1034159-49-3 N-(1-phenylethyl)-1-aminoadamantane 
• 1261081-97-3 AdNHC(CD₃)(C₆D₅) 
• 98969-45-0 N-(1-adamantyl)imidoethane 

Relevant articles and documents

Catalytic C - H amination with unactivated amines through copper(II) amides

En route to catalysis: Two equivalents of the three-coordinate copper(II) amide [(Cl2NN)Cu]-NHAd participate in stoichiometric C - H amination by a H-atom abstraction/radical capture sequence. This active species may be generated through a copper(II) tert-butoxide intermediate to allow for the unprecedented catalytic amination of sp3-C - H bonds with unactivated alkylamines. This method greatly expands the range of amines for catalytic C - H amination since most protocols require N-based electron-withdrawing groups.