Welcome to LookChem.com Sign In|Join Free

CAS

  • or
ethyl (phenylimino)acetate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

121642-09-9 Suppliers

Post Buying Request

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier
  • 121642-09-9 Structure
  • Basic information

    1. Product Name: ethyl (phenylimino)acetate
    2. Synonyms: ethyl (phenylimino)acetate
    3. CAS NO:121642-09-9
    4. Molecular Formula: C10H11NO2
    5. Molecular Weight: 177.19984
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 121642-09-9.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: ethyl (phenylimino)acetate(CAS DataBase Reference)
    10. NIST Chemistry Reference: ethyl (phenylimino)acetate(121642-09-9)
    11. EPA Substance Registry System: ethyl (phenylimino)acetate(121642-09-9)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 121642-09-9(Hazardous Substances Data)

121642-09-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 121642-09-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,1,6,4 and 2 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 121642-09:
(8*1)+(7*2)+(6*1)+(5*6)+(4*4)+(3*2)+(2*0)+(1*9)=89
89 % 10 = 9
So 121642-09-9 is a valid CAS Registry Number.

121642-09-9Relevant articles and documents

CuCl/air-mediated oxidative coupling reaction of imidazoheterocycles with N -aryl glycine esters

Jiao, Jing,Zhang, Jun-Rong,Liao, Yan-Yan,Xu, Li,Hu, Maolin,Tang, Ri-Yuan

, p. 30152 - 30159 (2017)

A copper/air mediated oxidative coupling reaction of imidazoheterocycles with N-aryl glycine esters is here described. The reaction proceeded effectively under an air atmosphere without the use of peroxide agents. This simple protocol allows for the preparation of a wide range of imidazoheterocycles with a glycine ester motif, which are of great interest in the field of medicinal chemistry. Interestingly, the coupling of imidazo[1,2-a]pyridine with secondary or tertiary α-amino phenylethanone selectively affords the imidazo[1,2-a]pyridin-3-yl imine or imidazo[1,2-a]pyridin-3-yl diketone in the presence of CuCl and TBHP (tertbutyl hydroperoxide).

Tin powder-promoted oxidation/allylation of glycine esters: Synthesis of γ,δ-unsaturated α-amino acid esters

Zhao, Pengfei,Huang, Danfeng,Wang, Feng,Han, Tongyu,Yang, Ming,Wang, Ke-Hu,Hu, Yulai

, (2021/10/20)

An efficient tin powder-promoted oxidation/allylation reaction of glycine esters with allyl bromides is developed, which affords γ,δ-unsaturated α-amino acid esters under mild conditions without any other transition metal catalysts. This method avoids the use of unstable imine as starting material, and provides an efficient method for synthesis of γ,δ-unsaturated α-amino acid esters and α-methylene-γ-lactam derivatives. Additional supporting information may be found in the online version of this article at the publisher's web site.

Unlocking the direct photocatalytic difluoromethylation of CN bonds

Alemán, José,Garrido-Castro, Alberto F.,Gini, Andrea,Maestro, M. Carmen

supporting information, p. 3769 - 3772 (2020/04/10)

The current study presents a direct CF2H radical addition to CN bonds predicated on the photocatalytic activation of commercially available zinc difluoromethanesulfinate. The mild conditions in place lead to impressive structural diversity, as quinoxalinones and dibenzazepines, among others, are successfully functionalized.

Visible-Light-Mediated, Chemo- and Stereoselective Radical Process for the Synthesis of C-Glycoamino Acids

Ji, Peng,Zhang, Yueteng,Wei, Yongyi,Huang, He,Hu, Wenbo,Mariano, Patrick A.,Wang, Wei

supporting information, p. 3086 - 3092 (2019/05/01)

An approach for efficient synthesis of C-glycosyl amino acids is described. Different from typical photoredox-catalyzed reactions of imines, the new process follows a pathway in which α-imino esters serve as electrophiles in chemoselective addition reactions with nucleophilic glycosyl radicals. The process is highlighted by the mild nature of the reaction conditions, the highly stereoselectivity attending C-C bond formation, and its applicability to C-glycosylations using both armed and disarmed pentose and hexose derivatives.

Polarity-Reversed Addition of Enol Ethers to Imines under Visible Light: Redox-Neutral Access to Azide-Containing Amino Acids

Yang, Sen,Zhu, Shuangyu,Lu, Dengfu,Gong, Yuefa

supporting information, p. 8464 - 8468 (2019/10/14)

A three-component and polarity-reversed addition cascade with a glyoxylate-based imine, an enol ether, and TMSN3 was established for the construction of γ-azido amino acids under visible light. This transformation features mild and redox-neutra

Asymmetric Organocatalytic Synthesis of Bisindoles – Scope and Derivatizations

Retich, Christina,Br?se, Stefan

supporting information, p. 60 - 77 (2018/01/17)

Starting from 3-vinylindoles and glyoxolate imines, we created a library of diverse 4,6-bis(1H-indole-3-yl)piperidine 2-carboxylates by using 10 mol-% of a chiral phosphoric acid. Utilising electron-withdrawing groups on the starting material during the r

Copper-Catalyzed Addition of Alkylboranes to Iminoacetates: Access to α-Alkyl Branched α-Amino Acids

Xiao, Xinsheng,Zhang, Wei,Lu, Xiaoxia,Deng, Yuanfu,Jiang, Huangfeng,Zeng, Wei

, p. 2497 - 2509 (2016/08/16)

A copper(I)-catalyzed addition of alkylborane reagents to α-iminoacetates has been developed to assemble both acyclic and cyclic α-branched α-amino carboxylic acid derivatives in good yields. A wide variety of unactivated alkenes are well tolerated in this transformation. (Figure presented.).

Reductive Umpolung of Carbonyl Derivatives with Visible-Light Photoredox Catalysis: Direct Access to Vicinal Diamines and Amino Alcohols via α-Amino Radicals and Ketyl Radicals

Fava, Eleonora,Millet, Anthony,Nakajima, Masaki,Loescher, Sebastian,Rueping, Magnus

supporting information, p. 6776 - 6779 (2016/06/09)

Visible-light-mediated photoredox-catalyzed aldimine-aniline and aldehyde-aniline couplings have been realized. The reductive single electron transfer (SET) umpolung of various carbonyl derivatives enabled the generation of intermediary ketyl and α-amino radical anions, which were utilized for the synthesis of unsymmetrically substituted 1,2-diamines and amino alcohols. Anilines can be coupled with aldimines or aldehydes in a visible-light-mediated photoredox-catalyzed process. Reductive single electron transfer (SET) umpolung of the carbonyl derivatives leads to the generation of intermediary ketyl and α-amino radical anions, which were used for the synthesis of unsymmetrically substituted 1,2-diamines and amino alcohols.

Synthesis of Dihydrophenanthridines and Oxoimidazolidines from Anilines and Ethylglyoxylate via Aza Diels-Alder Reaction of Arynes and KF-Induced Annulation

Reddy, R. Santhosh,Lagishetti, Chandraiah,Chen, Shuo,Kiran, I. N. Chaithanya,He, Yun

supporting information, p. 4546 - 4549 (2016/09/28)

The transition-metal-free multicomponent coupling of arynes, anilines, and ethylglyoxylate, proceeding via an inverse electron-demand aza Diels-Alder cycloaddition and N-arylation, has been demonstrated. This protocol allows rapid access to N-aryl dihydrophenanthridine derivatives in moderate to high yields at room temperature from readily available starting materials. In addition, an unprecedented fluoride induced annulation of ethyl(arylimino)acetates led to the formation of highly functionalized oxoimidazolidine derivatives in good yields under mild conditions.

Asymmetric organocatalytic synthesis of 4,6-bis(1H-indole-3-yl)-piperidine- 2 carboxylates

Zhong, Sabilla,Nieger, Martin,Bihlmeier, Angela,Shi, Min,Braese, Stefan

supporting information, p. 3265 - 3270 (2014/05/06)

We developed an asymmetric organocatalytic synthesis of 4,6-bis(1H-indole-3-yl)-piperidine-2-carboxylates using 10 mol% of a chiral phosphoric acid. The products, which are novel bisindole-piperidine-amino acid hybrids, can be obtained in one step from 3-

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 121642-09-9