121879-14-9Relevant articles and documents
Desymmetrizing Hydroformylation of Dihydromuconic Acid Diesters: Application to the Synthesis of (±)-Vindeburnol
Salacz, Laura,Charpentier, Cyrille,Suffert, Jean,Girard, Nicolas
, p. 2257 - 2262 (2017)
The desymmetrizing hydroformylation of internal alkenes derived from dihydromuconic acid is described. The study of this reaction afforded easy access to polyfunction aldehydes. After the evaluation of the reactivity of the dimethyl ester derivative with various primary amines, this methodology was used to design a rapid synthesis of (±)-vindeburnol from tryptamine in only two steps.
A Heterogeneous Pt-ReOx/C Catalyst for Making Renewable Adipates in One Step from Sugar Acids
Jang, Jun Hee,Ro, Insoo,Christopher, Phillip,Abu-Omar, Mahdi M.
, p. 95 - 109 (2021/01/12)
Renewable adipic acid is a value-added chemical for the production of bioderived nylon. Here, the one-step conversion of mucic acid to adipates was achieved in high yield through deoxydehydration (DODH) and catalytic transfer hydrogenation (CTH) by a bifunctional Pt-ReOx/C heterogeneous catalyst with isopropanol as solvent and reductant. The Pt-ReOx/C catalyst is reusable and was regenerated at least five times. The catalyst exhibits a broad substrate scope of various diols. Spectroscopic studies of Pt-ReOx/C revealed ReVII and Pt0 as the relevant species for DODH and CTH, respectively. Isotope labeling experiments support a monohydride mechanism for CTH over Pt. This work demonstrates a reusable bifunctional catalyst for a one-step valorization of sugar acids to a practical monomer, which opens the door to multifunctional catalysis streamlining valorization of biomass-derived molecules.
Preparation process and equipment of diisopropyl adipate
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Paragraph 0078-0119, (2021/07/01)
The invention relates to a preparation process of diisopropyl adipate. The finished product of diisopropyl adipate is obtained through esterification reaction, dealcoholization, distillation, water washing, dehydration and filtration. A homogeneous catalyst selected in the esterification reaction has high catalytic activity and improves the reaction efficiency, then a film evaporator is combined for separation and refining, a catalyst in the product is effectively removed, the product quality is improved, some impurities influencing the product quality are rapidly and effectively removed through warm water washing, and the obtained product is high in purity, can be stored for a long time, and has neglected corrosion to equipment and extremely small pollution to the environment. In addition, the invention also provides equipment for the preparation process of diisopropyl adipate. The equipment comprises a reaction kettle, a condenser, a water segregator, a distillation kettle, a dealcoholization tower, the film evaporator, a washing tank, a dehydrator, a filtering device and a finished product tank.