122214-17-9Relevant academic research and scientific papers
A Photoannulation Route to Naphthalenes from Cyclic Ketones
Olsen, Robert J.,Minniear, John C.,Overton, W. Mack,Sherrick, John M.
, p. 989 - 991 (2007/10/02)
A three-step annulation of cyclic ketones has been developed.Aldol condensation with an aromatic aldehyde followed by Wittig olefination produces a 1,3-diene, which undergoes oxidative photocyclization to produce a naphthalene derivative.Ketone ring sizes of C5 to C8 were annulated successfully.The sequence was also applied successfully to three methyl-substituted derivatives and one polycyclic case.
Palladium-catalyzed cross-coupling reaction of alkenylalkoxysilanes with aryl and alkenyl halides in the presence of a fluoride ion
Tamao,Kobayashi,Ito
, p. 6051 - 6054 (2007/10/02)
Alkenyl-monoalkoxydimethylsilanes, dialkoxymethylsilanes, and trialkoxysilanes undergo palladium catalyzed cross-coupling reaction with alkenyl and aryl halides in the presence of tetra-n-butylammonium fluoride. A one-pot transformation of a homopropargyl
