1228050-59-6Relevant articles and documents
Deoxygenative coupling of 2-aryl-ethanols catalyzed by unsymmetrical pyrazolyl-pyridinyl-triazole ruthenium
Cao, Fei,Duan, Zheng-Chao,Zhu, Haiyan,Wang, Dawei
, (2021/02/02)
A pyrazolyl-pyridinyl-triazole Ru complex was synthesized from unsymmetrical pyrazolyl-pyridinyl-triazole (PPT) skeleton ligand and characterized through X-ray crystallography. The corresponding heterogeneous pyrazolyl-pyridinyl-triazole Ru complexes on γ
Oxygenation of Simple Olefins through Selective Allylic C?C Bond Cleavage: A Direct Approach to Cinnamyl Aldehydes
Liu, Jianzhong,Wen, Xiaojin,Qin, Chong,Li, Xinyao,Luo, Xiao,Sun, Ao,Zhu, Bencong,Song, Song,Jiao, Ning
, p. 11940 - 11944 (2017/09/20)
A novel metal-free allylic C?C σ-bond cleavage of simple olefins to give valuable cinnamyl aldehydes is reported. 1,2-Aryl or alkyl migration through allylic C?C bond cleavage occurs in this transformation, which is assisted by an alkyl azide reagent. This method enables O-atom incorporation into simple unfunctionalized olefins to construct cinnamyl aldehydes. The reaction features simple hydrocarbon substrates, metal-free conditions, and high regio- and stereoselectivity.
FeCl3·6H2O-catalyzed selective reduction of allylic halides to alkenes with concomitant oxidation of benzylic alcohols to aldehydes
Zhang, Houcai,Liu, Ruiting,Zhou, Xigeng
, p. 282 - 288 (2014/03/21)
Iron-catalyzed direct reduction of allylic halides with benzylic alcohol was achieved, providing a new, simple, and efficient method for conducting highly regioselective hydrodehalogenation. This method not only features a readily available reductant, an