32704-49-7

Upstream product

• 108-94-1 cyclohexanone 
• 1279102-43-0 2-benzoylcyclohex-1-en-1-yl diethyl phosphate 
• 3580-38-9 2-Benzoylcyclohexanone 
• 100-58-3 phenylmagnesium bromide 
• 38127-47-8 2-bromocyclohex-1-ene-1-carbaldehyde 
• 917-54-4 methyllithium 
• 1228319-68-3 α-(2-bromocyclohexen-1-yl)benzyl alcohol 
• 1001386-09-9 (2-bromocyclohex-1-en-1-yl)(phenyl)methanone 
• 75-16-1 methylmagnesium bromide 

Downstream Products

• 1279102-60-1 (Z)-trimethyl((2-methylenecyclohexylidene)(phenyl)methoxy)silane 
• 1279102-82-7 6-(4-methoxyphenyl)-8-phenyl-1,2,3,4,5,6-hexahydronaphthalene 
• 1279102-89-4 7-deutero-6,8-diphenyl-1,2,3,4,5,6-hexahydronaphthalene 
• 1279102-70-3 6,8-diphenyl-1,2,3,4,5,6-hexahydronaphthalene 
• 1279102-71-4 (Z)-(2-methylenecyclohexylidene)(phenyl)methyl cinnamate 
• 1279102-79-2 6-(2-nitrophenyl)-8-phenyl-1,2,3,4,5,6-hexahydronaphthalene 
• 1279102-80-5 6-(2-methoxyphenyl)-8-phenyl-1,2,3,4,5,6-hexahydronaphthalene 
• 1279102-81-6 6-(3-bromophenyl)-8-phenyl-1,2,3,4,5,6-hexahydronaphthalene 
• 1279102-83-8 6-(2-bromocyclohex-1-en-1-yl)-8-phenyl-1,2,3,4,5,6-hexahydronaphthalene 
• 1279102-84-9 2-(4-phenyl-1,2,5,6,7,8-hexahydronaphthalen-2-yl)furan 

Relevant academic research and scientific papers

Photoredox-catalyzed stereoselective alkylation of enamides with: N -hydroxyphthalimide esters via decarboxylative cross-coupling reactions

Stereoselective β-C(sp2)-H alkylation of enamides with redox-active N-hydroxyphthalimide esters via a photoredox-catalyzed decarboxylative cross-coupling reaction is demonstrated. This methodology features operational simplicity, broad substrat

Enabling the development of N-Heterocyclic Carbene (NHC) catalyzed reactions: Practical methods for the preparation of 1-acyl-2-alkylcycloalkenes from cycloalkanones

The synthesis of 1-acyl-2-alkylcycloalkenes from a variety of cycloalkanones has been achieved via either-keto enol phosphates or-bromoenones. Both methods exploit simple and readily scalable transformations allowing the preparation of the desired compoun

N-heterocyclic carbene-catalyzed (4 + 2) cycloaddition/decarboxylation of silyl dienol ethers with α,β-unsaturated acid fluorides

Herein we report the first all-carbon N-heterocyclic carbene-catalyzed (4 + 2) cycloaddition. The reaction proceeds with α,β-unsaturated acid fluorides and silyl dienol ethers and produces 1,3-cyclohexadienes with complete diastereocontrol (dr >20:1) while demonstrating a new type of reaction cascade exploiting α,β-unsaturated acyl azoliums.