1279102-70-3

Basic information

• Product Name: 6,8-diphenyl-1,2,3,4,5,6-hexahydronaphthalene
• Synonyms: 6,8-diphenyl-1,2,3,4,5,6-hexahydronaphthalene
• CAS NO: 1279102-70-3
• Molecular Weight: 286.417
• Mol File: 1279102-70-3.mol

Chemical Properties

• CAS DataBase Reference: 6,8-diphenyl-1,2,3,4,5,6-hexahydronaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 6,8-diphenyl-1,2,3,4,5,6-hexahydronaphthalene(1279102-70-3)
• EPA Substance Registry System: 6,8-diphenyl-1,2,3,4,5,6-hexahydronaphthalene(1279102-70-3)

Safety Data

• Hazardous Substances Data: 1279102-70-3(Hazardous Substances Data)

Upstream product

• 1001386-09-9 (2-bromocyclohex-1-en-1-yl)(phenyl)methanone 
• 1228319-68-3 α-(2-bromocyclohexen-1-yl)benzyl alcohol 
• 1279102-60-1 (Z)-trimethyl((2-methylenecyclohexylidene)(phenyl)methoxy)silane 
• 38986-89-9 trans-cinnamoyl fluoride 
• 38127-47-8 2-bromocyclohex-1-ene-1-carbaldehyde 
• 140-10-3 (E)-3-phenylacrylic acid 
• 1279102-35-0 α-D-(E)-cinnamoyl fluoride 
• 38986-89-9 3-phenylacryloyl fluoride 
• 3580-38-9 2-Benzoylcyclohexanone 
• 32704-49-7 (2-methylcyclohex-1-en-1-yl)(phenyl)methanone 
• 1279102-43-0 2-benzoylcyclohex-1-en-1-yl diethyl phosphate 

Relevant articles and documents

Synthetic and quantum mechanical studies into the N- heterocyclic carbene catalyzed (4 + 2) cycloaddition

The N-heterocyclic carbene catalyzed (4 + 2) cycloaddition between α,β-unsaturated acid fluorides and TMS dienol ethers provides cyclohexene fused β-lactone intermediates stable below -20 °C. These can be intercepted reductively or with organolithium reag

N-heterocyclic carbene-catalyzed (4 + 2) cycloaddition/decarboxylation of silyl dienol ethers with α,β-unsaturated acid fluorides

Herein we report the first all-carbon N-heterocyclic carbene-catalyzed (4 + 2) cycloaddition. The reaction proceeds with α,β-unsaturated acid fluorides and silyl dienol ethers and produces 1,3-cyclohexadienes with complete diastereocontrol (dr >20:1) while demonstrating a new type of reaction cascade exploiting α,β-unsaturated acyl azoliums.