123271-34-1Relevant academic research and scientific papers
NOVEL CATALYST FOR POLYMERISATION
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Page/Page column 13, (2008/06/13)
The present invention relates to metal/organic complexes of Formula (I), (II), (III), (IV), (V) and (VI) that are useful as catalysts for the polymerisation of carbonyl- containing or cyclic monomers. Typical polymerisation reactions are, for example, tho
Allene synthesis by an asymmetric Baylis-Hillman style reaction on vinylphosphine oxides
Fox,Medlock,Vosser,Warren
, p. 2240 - 2249 (2007/10/03)
A novel reaction has been discovered with a mechanism similar to the Baylis-Hillman reaction. Reaction of a vinylic phosphine oxide with (R)-N-lithio-α-methylbenzylbenzylamine 2 in the presence of an aldehyde gave hydroxyphosphine oxides in good to moderate yields and moderate to poor enantioselectivities. The hydroxyphosphine oxides undergo the Horner-Wittig elimination reaction to produce allenes. Baylis-Hillman reactions of vinylic phosphine oxides with tertiary amines were also investigated.
Conformational Analysis of 2-Substituted Alkylphosphoryl Compounds. 4. Substituent Effect on the Nature of the Hydrogen Bonding in (2-Hydroxyalkyl)phosphoryl Systems
Genov, Daniel G.,Kresinski, Roman A.,Tebby, John C.
, p. 2574 - 2585 (2007/10/03)
The extent to which solid state conformational and hydrogen bonding preferences of five (2-hydroxyalkyl)phosphoryl compounds 2a-e [R12P(O)CH2CH(OH)R2; 2a, R1 = MeO, R2 = Ph; 2b, R1/su
