123427-34-9

Basic information

• Product Name: (4S,5R,2'R)-1,5-dimethyl-4-phenyl-3-(2'3'-dibenzyloxypropanoyl)imidazolidin-2-one
• Synonyms: (4S,5R,2'R)-1,5-dimethyl-4-phenyl-3-(2'3'-dibenzyloxypropanoyl)imidazolidin-2-one
• CAS NO: 123427-34-9
• Molecular Weight: 458.557
• Mol File: 123427-34-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4S,5R,2'R)-1,5-dimethyl-4-phenyl-3-(2'3'-dibenzyloxypropanoyl)imidazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,5R,2'R)-1,5-dimethyl-4-phenyl-3-(2'3'-dibenzyloxypropanoyl)imidazolidin-2-one(123427-34-9)
• EPA Substance Registry System: (4S,5R,2'R)-1,5-dimethyl-4-phenyl-3-(2'3'-dibenzyloxypropanoyl)imidazolidin-2-one(123427-34-9)

Safety Data

• Hazardous Substances Data: 123427-34-9(Hazardous Substances Data)

Upstream product

• 92841-65-1 (4R,5S)-1,5-dimethyl-4-phenylimidazolidin-2-one 
• 19810-31-2 Benzyloxyacetyl chloride 
• 3587-60-8 Benzyloxymethyl chloride 
• 123483-75-0 (4S,5R)-1-benzyloxyacetyl-3,4-dimethyl-5-phenyl-imidazolidin-2-one 
• 112791-04-5 (4R,5S)-3,4-dimethyl-5-phenyl-imidazolidin-2-one 
• 123394-73-0 (4S,5R)-1,5-dimethyl-4-phenyl-3-benzyloxyacetylimidazolidin-2-one 

Downstream Products

• 123394-81-0 (R)-1-propanoyloxy-2,3-dibenzyloxypropane 
• 20196-71-8 (2S)-2,3-bis(benzyloxy)propanol 

Relevant articles and documents

ENANTIOSELECTIVE SYNTHESIS OF 2-BENZYLOXY ALCOHOLS AND 1,2-DIOLS VIA ALKYLATION OF CHIRAL GLYCOLATE IMIDES. A CONVENIENT APPROACH TO OPTICALLY ACTIVE GLYCEROL DERIVATIVES

The alkylation of the chiral enolates of glycolate imides 2a and 2b proceedes in highly diastereoselective manner to give 2'-substituted products in good yield.Reductive cleavage with LiBH4 affords the corresponding 2-benzyloxyalcohols 3a-c and 11a-b which are successively converted to 1,2-diols in high optical purity.By this method (R)-1-propanoyloxy-2,3-propanediol 9 and (S)-1-tridecyloxy-2,3-propanediol 14, a glyceride extracted from sponges Plocamiidae, have been synthesized, starting from 2a and 2b, respectively.