123483-75-0

Upstream product

• 19810-31-2 Benzyloxyacetyl chloride 
• 92841-65-1 (4R,5S)-1,5-dimethyl-4-phenylimidazolidin-2-one 

Downstream Products

• 123394-76-3 (4R,5S,2'R)-1,5-dimethyl-4-phenyl-3-(2',3'-dibenzyloxy-3'-phenylpropanoyl)imidazoldin-2-one 
• 123394-76-3 (4R,5S,2'S)-1,5-dimethyl-4-phenyl-3-(2',3'-dibenzyloxy-3'-phenylpropanoyl)imidazoldin-2-one 
• 796965-82-7 Z-(4S,5R,2'S)-3,4-dimethyl-5-phenyl-1-(2'-benzyloxy-5',9'-dimethyldeca-4',8'-dienoyl)-imidazolidin-2-one 
• 123394-79-6 (S)-2-(benzyloxy)-1-hydroxy-3-phenylpropane 
• 123394-82-1 (R)-1-tridecyloxy-2,3-dibenzyloxypropane 
• 58530-76-0 (R)-2,3-dibenzyloxy-1-propanol 
• 796965-83-8 Z-(2S)-2-benzyloxy-N-methoxy-N,5,9-trimethyldeca-4,8-dienoylamide 

Relevant academic research and scientific papers

ENANTIOSELECTIVE SYNTHESIS OF 2-BENZYLOXY ALCOHOLS AND 1,2-DIOLS VIA ALKYLATION OF CHIRAL GLYCOLATE IMIDES. A CONVENIENT APPROACH TO OPTICALLY ACTIVE GLYCEROL DERIVATIVES

The alkylation of the chiral enolates of glycolate imides 2a and 2b proceedes in highly diastereoselective manner to give 2'-substituted products in good yield.Reductive cleavage with LiBH4 affords the corresponding 2-benzyloxyalcohols 3a-c and 11a-b which are successively converted to 1,2-diols in high optical purity.By this method (R)-1-propanoyloxy-2,3-propanediol 9 and (S)-1-tridecyloxy-2,3-propanediol 14, a glyceride extracted from sponges Plocamiidae, have been synthesized, starting from 2a and 2b, respectively.