123518-88-7

Basic information

• Product Name: Dithiocarbonic acid O-((1R,2R,3R,4R,5R)-2-benzyloxy-2,4-dimethyl-6,8-dioxa-bicyclo[3.2.1]oct-3-yl) ester S-methyl ester
• CAS NO: 123518-88-7
• Molecular Weight: 354.491
• Mol File: 123518-88-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Dithiocarbonic acid O-((1R,2R,3R,4R,5R)-2-benzyloxy-2,4-dimethyl-6,8-dioxa-bicyclo[3.2.1]oct-3-yl) ester S-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Dithiocarbonic acid O-((1R,2R,3R,4R,5R)-2-benzyloxy-2,4-dimethyl-6,8-dioxa-bicyclo[3.2.1]oct-3-yl) ester S-methyl ester(123518-88-7)
• EPA Substance Registry System: Dithiocarbonic acid O-((1R,2R,3R,4R,5R)-2-benzyloxy-2,4-dimethyl-6,8-dioxa-bicyclo[3.2.1]oct-3-yl) ester S-methyl ester(123518-88-7)

Safety Data

• Hazardous Substances Data: 123518-88-7(Hazardous Substances Data)

Upstream product

• 91510-63-3 4-O-Allyl-1,6:2,3-dianhydro-β-D-mannopyranose 
• 75-15-0 carbon disulfide 
• 81076-78-0 1,6-anhydro-2-desoxy-2,4-di-C-methyl-4-O-benzyl-β-D-galactopyranose 
• 74-88-4 methyl iodide 
• 123518-87-6 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-(4-methoxybenzyl)-4-O-benzyl-β-D-galactopyranose 
• 123493-63-0 1,6-anhydro-2-desoxy-2-C-methyl-4-O-allyl-3-O-(4-methoxybenzyl)-β-D-glucopyranose 
• 123493-65-2 1,6-anhydro-2-desoxy-2-C-methyl-3-O-(4-methoxybenzyl)-β-D-xylo-hexapyranoz-4-ylose 
• 123493-66-3 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-(4-methoxybenzyl)-β-D-galactopyranose 
• 123493-64-1 1,6-anhydro-2-desoxy-2-C-methyl-3-O-(4-methoxybenzyl)-β-D-glucopyranose 
• 91510-64-4 4-O-allyl-1,6-anhydro-2-deoxy-2-C-methyl-β-D-glucopyranose 

Downstream Products

• 134744-47-1 ((2R,3R,5R,6R)-3-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-methanol 
• 134744-28-8 ((2R,3R,5R,6S)-3-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-methanol 
• 123493-62-9 1,6-anhydro-2,3-didesoxy-2,4-di-C-methyl-4-O-benzyl-β-D-galactopyranose 

Relevant articles and documents

Stereocontrolled synthesis of erythronolides A and B in a (C5-C9) + (C3-C4) + (C1-C2) + (C11-C13) sequence from 1,6-anhydro-β-D-glycopyranose (levoglucosan). Part 1. Synthesis of C1-C10 and C11-C13 segments

An approach to the synthesis of aglycones of macrolide antibiotics erythromycin A and B is discussed and preparation of common C1-C10 and C11-C13 segments starting from levoglucosane is described.