134744-47-1

Basic information

• Product Name: ((2R,3R,5R,6R)-3-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-methanol
• CAS NO: 134744-47-1
• Molecular Weight: 280.364
• Mol File: 134744-47-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ((2R,3R,5R,6R)-3-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: ((2R,3R,5R,6R)-3-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-methanol(134744-47-1)
• EPA Substance Registry System: ((2R,3R,5R,6R)-3-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-methanol(134744-47-1)

Safety Data

• Hazardous Substances Data: 134744-47-1(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 123518-88-7 Dithiocarbonic acid O-((1R,2R,3R,4R,5R)-2-benzyloxy-2,4-dimethyl-6,8-dioxa-bicyclo[3.2.1]oct-3-yl) ester S-methyl ester 
• 91510-63-3 4-O-Allyl-1,6:2,3-dianhydro-β-D-mannopyranose 
• 123518-87-6 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-(4-methoxybenzyl)-4-O-benzyl-β-D-galactopyranose 
• 123493-63-0 1,6-anhydro-2-desoxy-2-C-methyl-4-O-allyl-3-O-(4-methoxybenzyl)-β-D-glucopyranose 
• 123493-65-2 1,6-anhydro-2-desoxy-2-C-methyl-3-O-(4-methoxybenzyl)-β-D-xylo-hexapyranoz-4-ylose 
• 123493-66-3 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-(4-methoxybenzyl)-β-D-galactopyranose 
• 123493-64-1 1,6-anhydro-2-desoxy-2-C-methyl-3-O-(4-methoxybenzyl)-β-D-glucopyranose 
• 81076-78-0 1,6-anhydro-2-desoxy-2,4-di-C-methyl-4-O-benzyl-β-D-galactopyranose 
• 91510-64-4 4-O-allyl-1,6-anhydro-2-deoxy-2-C-methyl-β-D-glucopyranose 
• 67-56-1 methanol 
• 123493-62-9 1,6-anhydro-2,3-didesoxy-2,4-di-C-methyl-4-O-benzyl-β-D-galactopyranose 

Downstream Products

• 114114-21-5 {(2R,4R)-4-Benzyloxy-4-[(2R,4R,5S,6R)-2-(4-methoxy-phenyl)-5-methyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-2-methyl-pentyloxy}-tert-butyl-dimethyl-silane 
• 134744-30-2 (2R,4R)-4-Benzyloxy-2,4-dimethyl-hex-5-en-1-ol 
• 114114-20-4 (2R,3R,4R,6R)-4-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,4,6-trimethyl-heptanal 
• 123493-56-1 [(2R,4R,5R,6S)-4-Benzyloxy-5-(4-methoxy-benzyloxy)-2,4,6-trimethyl-oct-7-enyloxy]-tert-butyl-dimethyl-silane 
• 123493-55-0 {(1R,2R,3S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-1,3-dimethyl-pent-4-enyloxymethyl}-benzene 
• 123618-89-3 {(1R,2R,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-1,3-dimethyl-pent-4-enyloxymethyl}-benzene 
• 114114-19-1 (3S,4R,5R,7R)-5-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-oct-1-en-4-ol 
• 114181-54-3 (3R,4R,5R,7R)-5-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-oct-1-en-4-ol 
• 123493-57-2 (2R,4R,5R,6S)-4-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-2,4,6-trimethyl-oct-7-en-1-ol 
• 123493-57-2 (2R,4R,5R,6R)-4-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-2,4,6-trimethyl-oct-7-en-1-ol 
• 114114-18-0 (2R,4R)-2-benzyloxy-5-tert-butyldimethylsiloxy-2,4-dimethylpentanal 
• 114114-30-6 (2R,3R,5R,6R)-3-Benzyloxy-6-methoxy-3,5-dimethyl-2-((S)-1-methyl-allyl)-tetrahydro-pyran 
• 114181-57-6 (2R,3R,5R,6R)-3-Benzyloxy-6-methoxy-3,5-dimethyl-2-((R)-1-methyl-allyl)-tetrahydro-pyran 
• 114137-89-2 (3S,4R,5S,6R,7R,9R)-7-Benzyloxy-10-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-3,5,7,9-tetramethyl-dec-1-en-4-ol 

Relevant articles and documents

Stereocontrolled synthesis of erythronolides A and B in a (C5-C9) + (C3-C4) + (C1-C2) + (C11-C13) sequence from 1,6-anhydro-β-D-glycopyranose (levoglucosan). Part 1. Synthesis of C1-C10 and C11-C13 segments

An approach to the synthesis of aglycones of macrolide antibiotics erythromycin A and B is discussed and preparation of common C1-C10 and C11-C13 segments starting from levoglucosane is described.