91510-63-3

Basic information

• Product Name: beta-D-Mannopyranose, 1,6:2,3-dianhydro-4-O-2-propenyl- (9CI)
• Synonyms: beta-D-Mannopyranose, 1,6:2,3-dianhydro-4-O-2-propenyl- (9CI)
• CAS NO: 91510-63-3
• Molecular Formula: C₉H₁₂O₄
• Molecular Weight: 184.18918
• Product Categories: EPOXYDE
• Mol File: 91510-63-3.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: beta-D-Mannopyranose, 1,6:2,3-dianhydro-4-O-2-propenyl- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: beta-D-Mannopyranose, 1,6:2,3-dianhydro-4-O-2-propenyl- (9CI)(91510-63-3)
• EPA Substance Registry System: beta-D-Mannopyranose, 1,6:2,3-dianhydro-4-O-2-propenyl- (9CI)(91510-63-3)

Safety Data

• Hazardous Substances Data: 91510-63-3(Hazardous Substances Data)

Upstream product

• 107-18-6 allyl alcohol 
• 498-07-7 levoglucosan 
• 6167-32-4 1,6:3,4-dianhydro-2-O-tosyl-D-galactose 
• 13265-84-4 D-glucal 
• 139437-39-1 1,6-anhydro-2-deoxy-2-iodo-β-D-glucopyranose 
• 106-95-6 allyl bromide 
• 3868-03-9 1,6:2,3-dianhydro-β-D-mannopyranose 
• 39697-97-7 4-O-Allyl-1,6-anhydro-2-O-tosyl-β-D-glucopyranose 

Downstream Products

• 133782-37-3 (2S,3R)-2-<(benzyloxy)methoxy>-3-<(tert-butyldimethylsilyl)oxy>-2-methylpentanal 
• 134744-47-1 ((2R,3R,5R,6R)-3-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-methanol 
• 134744-28-8 ((2R,3R,5R,6S)-3-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-methanol 
• 90074-16-1 (2R,3R)-2,3-<(R)-(4-methoxybenzylidene)dioxy>-2-methylpentanal 
• 134876-43-0 (2S,4S,5R)-5-Ethyl-2-(4-methoxy-phenyl)-4-methyl-4-vinyl-[1,3]dioxolane 
• 134744-44-8 (2R,4S,5R)-5-Ethyl-2-(4-methoxy-phenyl)-4-methyl-4-vinyl-[1,3]dioxolane 
• 134744-39-1 Benzoic acid (3R,4S)-4-benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hex-5-enyl ester 
• 134744-42-6 Benzoic acid 2-[(2R,4R,5S)-2-(4-methoxy-phenyl)-5-methyl-5-vinyl-[1,3]dioxolan-4-yl]-ethyl ester 
• 123518-88-7 Dithiocarbonic acid O-((1R,2R,3R,4R,5R)-2-benzyloxy-2,4-dimethyl-6,8-dioxa-bicyclo[3.2.1]oct-3-yl) ester S-methyl ester 
• 134744-40-4 (3R,4S)-4-Benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hex-5-en-1-ol 
• 134744-38-0 Benzoic acid (3R,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-4-methyl-hex-5-enyl ester 
• 134744-32-4 (1R,2S,3R,5R)-2-Allyloxy-3-benzyloxymethoxy-6,8-dioxa-bicyclo[3.2.1]octane 
• 134744-41-5 ((1R,2S)-2-Benzyloxymethoxy-1-ethyl-2-methyl-but-3-enyloxy)-tert-butyl-dimethyl-silane 
• 134744-34-6 (1R,3R,5R)-3-Benzyloxymethoxy-6,8-dioxa-bicyclo[3.2.1]octan-2-one 

Relevant articles and documents

A facile synthesis of Cerny epoxides and selectively blocked derivatives of 2-azido-2-deoxy-β-D-glucopyranose

1,6:2,3-Dianhydro-β-D-glucopyranose and its 3-alkylated derivatives were prepared from D-glucal in one pot with overall isolated yields of 60-70%, and these Cerny epoxides were further conveniently converted to selectively blocked 2-azido-2-deoxy-β-D-glucopyranose derivatives by azido opening of the epoxide ring.

Opening of levoglucosane derived epoxides with oxygen, nitrogen and sulfur nucleophiles

A variety of nucleophiles were employed to open levoglucosane derived epoxides.

Synthesis of macrolide antibiotics. 3. Revised synthesis of C9-C13 segment of erythronolide A

-