123707-26-6Relevant articles and documents
Synthesis of a C1-C21 subunit of the protein phosphatase inhibitor tautomycin: A formal total synthesis
Marshall,Yanik
, p. 1373 - 1379 (2007/10/03)
The synthesis of a C1-C21 subunit of tautomycin is described. The convergent route employs enantioenriched allenylstannane and zinc reagents derived from (S)-3-butyn-2-ol methanesulfonate. These reagents react with appropriate aldehyde segments to yield s
TANDEM ORGANOMETALLIC ADDITION REACTIONS TO N-METHOXY-UREAS AND URETHANES IN THE PREPARATION OF UNSYMMETRICAL AND SYMMETRICAL KETONES
Hlasta, Dennis J.,Court, John J.
, p. 1773 - 1776 (2007/10/02)
The use of novel reagents 1a-c for the synthesis of ketones in a one pot reaction is described.An interesting leaving group effect was discovered in the fragmentation of the proposed complexes 2 to the intermediate N-methoxyamides 3.