1241376-37-3Relevant academic research and scientific papers
Rhodium and iridium complexes containing diphenyl-2-(3-methyl) indolylphosphine: Synthesis, structure and application in the catalytic transfer hydrogenation of ketones
Kuo, Yu-Ying,Haddow, Mairi F.,Perez-Redondo, Adrian,Owen, Gareth R.
, p. 6239 - 6248 (2010/09/06)
The synthesis and characterisation of a number of group nine complexes containing the recently reported ligand, diphenyl-2-(3-methyl)indolylphosphine, is presented herein. The complexes [RhCl(COD){PPh2(C 9H8N)}] (1), [IrCl(COD){PPh2(C 9H8N)}] (2), [RhCl(NBD){PPh2(C 9H8N)}] (3) and [Rh(COD)(MeCN){PPh2(C 9H8N)}]BF4 (4) (where COD = 1,5-cyclooctadiene, NBD = 2,5- norbornadiene) have been structurally characterised by X-ray crystallography. The complex [Rh2(COD)2{N(Me)C(H)Ph)} {PPh2(C9H8N)}][BF4]2 (8) was also isolated and structurally characterised. Complex 8 contains a '[Rh(COD)]' fragment coordinated to the aromatic ring of the indolyl group, providing the first example of a η6 coordination mode for this ligand. The synthesised complexes were investigated for their activity in the catalytic transfer hydrogenation of ketones and found to be moderately active catalysts.
