1242065-83-3Relevant academic research and scientific papers
A stereoselective total synthesis of decarestrictine I
Yadav, Jhillu Singh,Venkatesh, Miriyal,Kumar, Alleni Suman,Reddy, Poli Adi Narayana,Reddy, Basi V. Subba,Prasad, Attaluri R.
, p. 830 - 838 (2014/07/07)
A convergent and stereoselective total synthesis of decarestrictine I, a polyketide natural product, is described. Both acid and alcohol fragments were prepared from the readily available L-malic acid via Still-Gennari olefination and Sharpless asymmetric epoxidation. The Steglich esterification and ring-closing metathesis (RCM) are employed to combine both acid and alcohol fragments. Copyright
Total synthesis of decarestrictine i and botryolide B via RCM protocol
Radha Krishna, Palakodety,Rao, T. Jagannadha
supporting information; experimental part, p. 3130 - 3132 (2010/08/21)
A convergent stereoselective total synthesis of decarestrictine I (1) and botryolide B (1a) invoking a common synthetic strategy is reported. The key steps are: ring-closing metathesis of epoxy dienoic esters obtained through the Yamaguchi esterification
