1246182-86-4Relevant academic research and scientific papers
Nucleophilic substitution catalyzed by a supramolecular cavity proceeds with retention of absolute stereochemistry
Zhao, Chen,Toste, F. Dean,Raymond, Kenneth N.,Bergman, Robert G.
, p. 14409 - 14412 (2014)
While the reactive pocket of many enzymes has been shown to modify reactions of substrates by changing their chemical properties, examples of reactions whose stereochemical course is completely reversed are exceedingly rare. We report herein a class of wa
Selection of chiral zinc catalysts for the kinetic resolution of esters via dynamic templating
Kannappan,Nicholas
, p. 90 - 100 (2013/04/10)
Dynamic combinatorial libraries of chiral tetradentate bis-imine zinc(II) complexes have been prepared and screened for (1) their discrimination of enantiomeric picolinate esters and pyridyl phosphonate transition state analogs (TSAs) and (2) their cataly
