124941-48-6Relevant academic research and scientific papers
Stereocontrol in a combined allylic azide rearrangement and intramolecular schmidt reaction
Liu, Ruzhang,Gutierrez, Osvaldo,Tantillo, Dean J.,Aube, Jeffrey
, p. 6528 - 6531 (2012/06/15)
Pre-equilibration of an interconverting set of isomeric allylic azides is coupled with an intramolecular Schmidt reaction to afford substituted lactams stereoselectively. The effect of substitution and a preliminary mechanistic study are reported. The syn
Stereospecific total synthesis of amberketal and a homologue
Kongkathip, Boonsong,Kongkathip, Ngampong,Janthorn, Sirinan,Virarangsiyakorn, Duangmanee
, p. 51 - 52 (2007/10/03)
Amberketal (1a) and acetal homologue (2a) have been synthesised from a commercially available methyl acetoacetate involving palladium catalysed cyclisation as a key step.
