125257-45-6Relevant articles and documents
Enantio- and stereoselective syntheses of monodeuterium-labeled glycerols
Yagi,Oikawa,Ichihara
, p. 1038 - 1040 (2007/10/03)
An efficient method is described for synthesizing and four possible diastereomers of stereochemically defined monodeuterated glycerols by utilizing Sharpless asymmetric dihydroxylation.
Synthesis and Characterization of Chirally Deuteriated sn-Glycerols
Nishida, Yoshihiro,Uzawa, Hirotaka,Hanada, Shizu,Ohrui, Hiroshi,Meguro, Hiroshi
, p. 2319 - 2326 (2007/10/02)
(1S)--sn-Glycerol (1a) was obtained in three steps from (6S)--1,6-anhydro-β-D-galactopyranose and coverted to the (1R)-isomer (1b) via an SN2 reaction of a 1-O-methanesulfonylated derivative.The 1H and 13C-NMR spectra well character
Synthesis and Characterizations of Chirally Deuteriated Glycerols
Uzawa, Hirotaka,Nishida, Yoshihiro,Hanada, Shizu,Ohrui, Hiroshi,Meguro, Hiroshi
, p. 862 - 863 (2007/10/02)
(1S)- and (1R)--sn-Glycerols (1a) and (1b) have been stereoselectively synthsized from 1,6-anhydro-β-D-galactopyranose and characterized by 1H and 13C n.m.r. spectroscopy.