125783-57-5

Basic information

• Product Name: (1S)-(1-2H)-2,3-di-O-benzyl-sn-glycerol
• CAS NO: 125783-57-5
• Molecular Weight: 273.336
• Mol File: 125783-57-5.mol

Chemical Properties

• CAS DataBase Reference: (1S)-(1-2H)-2,3-di-O-benzyl-sn-glycerol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S)-(1-2H)-2,3-di-O-benzyl-sn-glycerol(125783-57-5)
• EPA Substance Registry System: (1S)-(1-2H)-2,3-di-O-benzyl-sn-glycerol(125783-57-5)

Safety Data

• Hazardous Substances Data: 125783-57-5(Hazardous Substances Data)

Upstream product

• 125257-44-5 (1S)-(1-2H)-1,2-O-(2-O-benzyloxyethylidene)-3-O-benzyl-sn-glycerol 
• 125257-46-7 (1S)-(1-2H)-1-O-^tbutyldimethylsilyl-3-O-benzyl-sn-glycerol 
• 125257-45-6 (1S)-(1-2H)-3-O-benzyl-sn-glycerol 
• 100-39-0 benzyl bromide 
• 15082-42-5 lithium benzyloxide 
• 110744-89-3 (2S,6R)-4-((S)-2-Benzyloxy-1-bromo-ethyl)-2,9,9-trimethyl-3,5-dioxa-4-bora-tricyclo[6.1.1.0^2,6]decane 
• 74-95-3 1,1-dibromomethane 

Downstream Products

• 125257-49-0 (1R)-(1-2H)-1-O-benzoyl-2,3-di-O-benzyl-sn-glycerol 
• 125783-59-7 (1R)-(1-2H)-2,3-di-O-benzyl-sn-glycerol 
• 125284-04-0 C₁₈H₂₁⁽²⁾HO₅S 

Relevant articles and documents

Synthesis of asymmetrically deuterated glycerol and dibenzylglyceraldehyde via boronic esters

(S)-Pinanediol [(benzyloxy)methyl]boronate (1a) has been converted via an improved procedure to (S)-pinanediol (1R)-[1,2-bis(benzyloxy)ethyl]boronate (3a) (96% de), which with (dibromomethyl)lithium has yielded (S)-pinanediol (1S,2S)-[2,3-benzyloxy)-1-bro

Synthesis and Characterizations of Chirally Deuteriated Glycerols

(1S)- and (1R)--sn-Glycerols (1a) and (1b) have been stereoselectively synthsized from 1,6-anhydro-β-D-galactopyranose and characterized by 1H and 13C n.m.r. spectroscopy.

Synthesis and Characterization of Chirally Deuteriated sn-Glycerols

(1S)--sn-Glycerol (1a) was obtained in three steps from (6S)--1,6-anhydro-β-D-galactopyranose and coverted to the (1R)-isomer (1b) via an SN2 reaction of a 1-O-methanesulfonylated derivative.The 1H and 13C-NMR spectra well character