125258-70-0Relevant academic research and scientific papers
Asymmetric synthesis of R-α-methyl-o-methoxybenzyl methyl ether via the diastereoselective functionalisation of (+)-(o-methoxybenzyl methyl ether)chromium tricarbonyl
Davies, Stephen G.,Goodfellow, Craig L.
, p. C5 - C8 (1989)
α-Methylation of (+)-(o-methoxybenzyl methyl ether)Cr(CO)3 occurs completely stereoselectively to yield, after decomplexation, homochiral R-α-methyl-o-methoxybenzyl methyl ether.
Asymmetric synthesis of (R)-(+)-α-methyl-o-methoxybenzyl methyl ether via the stereoselective benzylic elaboration of tricarbonyl (η6-o-methoxybenzyl methyl ether)chromium(o)
Davies,Goodfellow,Sutton
, p. 1303 - 1316 (1992)
Treatment of tricarbonyl (η6-o-methoxybenzyl methyl ether)chromium(o) with t-butyllithium followed by an electrophile gives a single diastereoisomer of the corresponding alpha substituted complex. The relative configuration within the product f
