125344-82-3

Upstream product

• 78-79-5 isoprene 
• 707-61-9 3-Methyl-1-phenyl-2-phospholene 1-oxide 
• 824-72-6 P,P-dichlorophenylphosphine oxide 
• 333-20-0 potassium thioacyanate 
• 42408-51-5 2-Bromo-3-hydroxy-3-methyl-1-phenylphospholane 1-oxide 

Relevant academic research and scientific papers

Phospho Sugars; Novel Preparation and Their Glycosyl Compounds

Treatment of 1-phenyl-2-, and -3-phospholene 1-oxides with N-bromosuccinimide affords 4-bromo-1-phenyl-2-phospholene 1-oxide.Substitution of the bromide with acetate, followed by stereoselective oxidation with osmium tetroxide and peracetylation with acetic anhydride/pyridine affords phospho sugar derivatives of tetrafuranose.Furthermore, N-, O-, and S-glycosyl compounds of phospho sugars can be prepared from 3-methyl-1-phenyl-2-phospholene 1-oxide by bromination and nucleophilic substitution reactions.This is a novel and excellent route to prepare phospho sugar derivatives.