1254970-97-2

Upstream product

• 186581-53-3 diazomethane 
• 1254970-95-0 N-nitro-О-(4-nitrophenyl)hydroxylamine 
• 74-88-4 methyl iodide 
• 33543-55-4 p-nitrophenoxyamine 

Downstream Products

• 51-28-5 2,4-Dinitrophenol 
• 100-02-7 4-nitro-phenol 
• 1394833-12-5 2-hydroxy-5-nitrophenyl trifluoromethylsulfonate 
• 3316-09-4 1,2-dihydroxy-4-nitrobenzene 
• 20110-52-5 5-nitro-1,3,2λ⁶-benzodioxathiol-2,2-dione 
• 1394833-11-4 2-hydroxy-5-nitrophenyl methylsulfonate 

Relevant academic research and scientific papers

Synthesis and properties of N-nitro-O-(4-nitrophenyl)hydroxylamine

Salts of N-nitro-O-(4-nitrophenyl)hydroxylamine were synthesized by a new method of oxidative nitration, involving the reaction of O-(4-nitrophenyl) hydroxylamine with KNO2 or NaNO2 in the presence of PhI(OAc)2 or PhIO as oxidants. When using Na15NO 2, the samples containing the nitro group labeled with the 15N isotope were obtained. Acidification of the appropriate salt gave N-nitro-O-(4-nitrophenyl)hydroxylamine. It is the first N-nitrohydroxylamine isolated in the H-form. Its thermal stability was investigated and the probable mechanism of decomposition was suggested. From a comparison of the 14N and 15N NMR spectra of N-nitro-O-(4-nitrophenyl) hydroxylamine with those of its O- and N-methylated derivatives, its equilibrium with the aci-form (N=NOOH) was inferred.