125620-61-3Relevant academic research and scientific papers
Reaction of cyanotrimethylsilane with oxiranes under Yb(CN)3 catalysis
Matsubara, Seijiro,Onishi, Hitoshi,Utimoto, Kiitiro
, p. 6209 - 6212 (1990)
Reaction of R3Yb, prepared from YbCl3 and RLi, with Me3SiCN gives Yb(CN)3, which is a highly efficient catalyst for regio and stereoselective cleavage of an oxirane with Me3SiCN under mild conditions
Addition of α-Halonitriles to Carbonyl Compounds Catalyzed by Zinc-Trimethylchlorosilane: A General Synthesis of β-Trimethylsiloxy Nitriles
Palomo, Claudio,Aizpurua, Jesus M.,Lopez, M. Concepcion,Aurrekoetxea, Natalia
, p. 2205 - 2208 (2007/10/02)
Reaction between bromoacetonitrile and carbonyl compounds in the presence of zinc and trimethylchlorosilane produced β-trimethylsilyloxynitriles in excellent yields.The reaction also works well with chloroacetonitrile as source of cyanomethyl carbanion.
