Reaction of cyanotrimethylsilane with oxiranes under Yb(CN)3 catalysis

DOI: 10.1016/S0040-4039(00)97026-6

Source and publish data:

Tetrahedron Letters p. 6209 - 6212 (1990)

Update date:2022-07-29

Topics:

Authors:

Matsubara, Seijiro

Onishi, Hitoshi

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/S0040-4039(00)97026-6

Reaction of R₃Yb, prepared from YbCl₃ and RLi, with Me₃SiCN gives Yb(CN)₃, which is a highly efficient catalyst for regio and stereoselective cleavage of an oxirane with Me₃SiCN under mild conditions

Full text of DOI:10.1016/S0040-4039(00)97026-6

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